Development of Imino-λ³-iodanes with Improved Reactivity for Metal-Free [2+2+1] Cycloaddition-Type Reactions

Takafumi Baba, Shunsuke Takahashi, Yui Kambara, Akira Yoshimura, Victor N. Nemykin, Viktor V. Zhdankin, Akio Saito

Исследовательская школа химических и биомедицинских технологий

Результат исследований: Материалы для журнала › Статья › рецензирование

Аннотация

Aiming at the enhancement of electrophilicity of imino-λ³-iodanes, we have developed (tosylimino)pentafluorophenyl-λ³-iodane, which shows superior reactivity compared to the commonly used (tosylimino)phenyl-λ³-iodane in the [2+2+1]-type synthesis of imidazoles. (Figure presented.).

Язык оригинала	Английский
Страницы (с-по)	3860-3864
Число страниц	5
Журнал	Advanced Synthesis and Catalysis
Том	359
Номер выпуска	21
DOI	https://doi.org/10.1002/adsc.201700934
Состояние	Опубликовано - 10 ноя 2017

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Доступ к документу

10.1002/adsc.201700934

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Development of Imino-λ³-iodanes with Improved Reactivity for Metal-Free [2+2+1] Cycloaddition-Type Reactions. / Baba, Takafumi; Takahashi, Shunsuke; Kambara, Yui; Yoshimura, Akira; Nemykin, Victor N.; Zhdankin, Viktor V.; Saito, Akio.

В: Advanced Synthesis and Catalysis, Том 359, № 21, 10.11.2017, стр. 3860-3864.

Результат исследований: Материалы для журнала › Статья › рецензирование

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title = "Development of Imino-λ3-iodanes with Improved Reactivity for Metal-Free [2+2+1] Cycloaddition-Type Reactions",

abstract = "Aiming at the enhancement of electrophilicity of imino-λ3-iodanes, we have developed (tosylimino)pentafluorophenyl-λ3-iodane, which shows superior reactivity compared to the commonly used (tosylimino)phenyl-λ3-iodane in the [2+2+1]-type synthesis of imidazoles. (Figure presented.).",

keywords = "Alkynes, cycloaddition, imidazoles, iminoiodanes, metal-free",

author = "Takafumi Baba and Shunsuke Takahashi and Yui Kambara and Akira Yoshimura and Nemykin, {Victor N.} and Zhdankin, {Viktor V.} and Akio Saito",

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T1 - Development of Imino-λ3-iodanes with Improved Reactivity for Metal-Free [2+2+1] Cycloaddition-Type Reactions

AU - Baba, Takafumi

AU - Takahashi, Shunsuke

AU - Kambara, Yui

AU - Yoshimura, Akira

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor V.

AU - Saito, Akio

PY - 2017/11/10

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N2 - Aiming at the enhancement of electrophilicity of imino-λ3-iodanes, we have developed (tosylimino)pentafluorophenyl-λ3-iodane, which shows superior reactivity compared to the commonly used (tosylimino)phenyl-λ3-iodane in the [2+2+1]-type synthesis of imidazoles. (Figure presented.).

AB - Aiming at the enhancement of electrophilicity of imino-λ3-iodanes, we have developed (tosylimino)pentafluorophenyl-λ3-iodane, which shows superior reactivity compared to the commonly used (tosylimino)phenyl-λ3-iodane in the [2+2+1]-type synthesis of imidazoles. (Figure presented.).

KW - Alkynes

KW - cycloaddition

KW - imidazoles

KW - iminoiodanes

KW - metal-free

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