Determination of Unsaturation Level, Halogen Content, and Main Forms of Isoprene Units in Halogenated Butyl Rubbers by 1H NMR Spectroscopy

I. I. Smolentseva, V. I. Mashukov, E. I. Korotkova

Результат исследований: Материалы для журналаСтатья

2 Цитирования (Scopus)

Выдержка

We have used1H NMR spectroscopy to study commercial samples of chloro-substituted and bromo-substituted butyl rubbers. We propose calculation formulas for quantitative determination of the main forms in halobutyl rubber (1,4-isoprene, exo form) and its characteristics: unsaturation level, halogen content in the isoprene units. We show that it is possible to determine the main structural characteristics of bromobutyl rubber in the presence of filler.

Язык оригиналаАнглийский
Страницы (с-по)465-469
Число страниц5
ЖурналJournal of Applied Spectroscopy
Том82
Номер выпуска3
DOI
СостояниеОпубликовано - 1 июл 2015

Отпечаток

Halogens
Rubber
rubber
halogens
Nuclear magnetic resonance spectroscopy
nuclear magnetic resonance
spectroscopy
Fillers
fillers
isoprene
butyl rubber

ASJC Scopus subject areas

  • Spectroscopy
  • Condensed Matter Physics

Цитировать

Determination of Unsaturation Level, Halogen Content, and Main Forms of Isoprene Units in Halogenated Butyl Rubbers by 1H NMR Spectroscopy. / Smolentseva, I. I.; Mashukov, V. I.; Korotkova, E. I.

В: Journal of Applied Spectroscopy, Том 82, № 3, 01.07.2015, стр. 465-469.

Результат исследований: Материалы для журналаСтатья

@article{264d4a62cb794984a7eefd4a278d67a9,
title = "Determination of Unsaturation Level, Halogen Content, and Main Forms of Isoprene Units in Halogenated Butyl Rubbers by 1H NMR Spectroscopy",
abstract = "We have used1H NMR spectroscopy to study commercial samples of chloro-substituted and bromo-substituted butyl rubbers. We propose calculation formulas for quantitative determination of the main forms in halobutyl rubber (1,4-isoprene, exo form) and its characteristics: unsaturation level, halogen content in the isoprene units. We show that it is possible to determine the main structural characteristics of bromobutyl rubber in the presence of filler.",
keywords = "filler, halogen content, halogenated butyl rubber, NMR spectroscopy, structural characteristics, unsaturation level",
author = "Smolentseva, {I. I.} and Mashukov, {V. I.} and Korotkova, {E. I.}",
year = "2015",
month = "7",
day = "1",
doi = "10.1007/s10812-015-0131-y",
language = "English",
volume = "82",
pages = "465--469",
journal = "Journal of Applied Spectroscopy",
issn = "0021-9037",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "3",

}

TY - JOUR

T1 - Determination of Unsaturation Level, Halogen Content, and Main Forms of Isoprene Units in Halogenated Butyl Rubbers by 1H NMR Spectroscopy

AU - Smolentseva, I. I.

AU - Mashukov, V. I.

AU - Korotkova, E. I.

PY - 2015/7/1

Y1 - 2015/7/1

N2 - We have used1H NMR spectroscopy to study commercial samples of chloro-substituted and bromo-substituted butyl rubbers. We propose calculation formulas for quantitative determination of the main forms in halobutyl rubber (1,4-isoprene, exo form) and its characteristics: unsaturation level, halogen content in the isoprene units. We show that it is possible to determine the main structural characteristics of bromobutyl rubber in the presence of filler.

AB - We have used1H NMR spectroscopy to study commercial samples of chloro-substituted and bromo-substituted butyl rubbers. We propose calculation formulas for quantitative determination of the main forms in halobutyl rubber (1,4-isoprene, exo form) and its characteristics: unsaturation level, halogen content in the isoprene units. We show that it is possible to determine the main structural characteristics of bromobutyl rubber in the presence of filler.

KW - filler

KW - halogen content

KW - halogenated butyl rubber

KW - NMR spectroscopy

KW - structural characteristics

KW - unsaturation level

UR - http://www.scopus.com/inward/record.url?scp=84956709673&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84956709673&partnerID=8YFLogxK

U2 - 10.1007/s10812-015-0131-y

DO - 10.1007/s10812-015-0131-y

M3 - Article

AN - SCOPUS:84956709673

VL - 82

SP - 465

EP - 469

JO - Journal of Applied Spectroscopy

JF - Journal of Applied Spectroscopy

SN - 0021-9037

IS - 3

ER -