Determination of 2,4,6-trinitrophenol by differential pulse voltammetry at a bismuth bulk working electrode

Vit Prchal, Vlastimil Vyskocil, Jiri Barek

Результат исследований: Материалы для журналаСтатья

6 Цитирования (Scopus)

Аннотация

A new method for differential pulse voltammetric determination of the priority pollutant 2,4,6-trinitrophenol (picric acid) on a bismuth bulk electrode using evaluation of the signal based on polynomial baseline fitting and subtraction is reported. Linear calibration curves were obtained in an acetate buffer (pH 4.0) solution from 2 × 10−6 to 1 × 10−4 mol L−1 of 2,4,6-trinitrophenol, with limits of detection and quantification of 2.0 × 10−7 mol L−1 and 6.7 × 10−7 mol L−1, respectively. The newly developed method was tested on real sample matrices of drinking and river water.

Язык оригиналаАнглийский
Страницы (с-по)H316-H320
ЖурналJournal of the Electrochemical Society
Том164
Номер выпуска6
DOI
СостояниеОпубликовано - 1 янв 2017
Опубликовано для внешнего пользованияДа

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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