Crystal structures of new double complex salts [M(NH3) 5Br][AuBr4]2·H2O, where M = Ir, Rh and complex salt [Ir(NH3)5Br]Br2

Аннотация

The crystal structures of double complex salts [M(NH₃) ₅Br][AuBr₄]₂·H₂O (M = Ir, Rh) are determined by single crystal XRD. The compounds crystallize in the triclinic system, P-1 space group, Z = 4. Crystallographic characteristics: [Ir(NH₃)₅Br][AuBr₄]₂·H ₂O: a = 8.2982(3) Å, b = 15.3045(4) Å, c = 17.4378(6) Å, α = 73.064(1)°, β = 88.938(1)°, γ = 86.221(1)°, V = 2113.95(12) Å³, d_x = 4.419 g/cm³, R = 0.0469; [Rh(NH₃)₅Br][AuBr ₄]²·H₂O: a = 8.2855(2) Å, b = 15.2881(3) Å, c = 17.4053(4) Å, α = 73.015(1)°, β = 88.913(1)°, γ = 86.267(1)°, V = 2104.08(8) Å³, d_x = 4.165 g/sm³, R = 0.0480. The crystal structure of [Ir(NH₃)₅Br]Br₂ is determined. The compound crystallizes in the orthorhombic system, Pnma space group, Z = 4. Crystallographic characteristics: a = 13.8521(3) Å, b = 10.8570(2) Å, c = 6.9908(1) Å, V = 1049.31(3) Å³, d _x = 3.273 g/cm³, R = 0.0127.

Язык оригинала	Английский
Страницы (с-по)	383-388
Число страниц	6
Журнал	Journal of Structural Chemistry
Том	52
Номер выпуска	2
DOI	https://doi.org/10.1134/S002247661102020X
Состояние	Опубликовано - апр 2011
Опубликовано для внешнего пользования	Да

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Доступ к документу

10.1134/S002247661102020X

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Crystal structures of new double complex salts [M(NH₃) ₅Br][AuBr₄]₂·H₂O, where M = Ir, Rh and complex salt [Ir(NH₃)₅Br]Br₂. / Plyusnin, P. E.; Semitut, E. Yu; Baidina, I. A.; Korenev, S. V.

В: Journal of Structural Chemistry, Том 52, № 2, 04.2011, стр. 383-388.

Результат исследований: Материалы для журнала › Статья › рецензирование

@article{7974e5b1c96243c79d0b317eaa89a09c,

title = "Crystal structures of new double complex salts [M(NH3) 5Br][AuBr4]2·H2O, where M = Ir, Rh and complex salt [Ir(NH3)5Br]Br2",

abstract = "The crystal structures of double complex salts [M(NH3) 5Br][AuBr4]2·H2O (M = Ir, Rh) are determined by single crystal XRD. The compounds crystallize in the triclinic system, P-1 space group, Z = 4. Crystallographic characteristics: [Ir(NH3)5Br][AuBr4]2·H 2O: a = 8.2982(3) {\AA}, b = 15.3045(4) {\AA}, c = 17.4378(6) {\AA}, α = 73.064(1)°, β = 88.938(1)°, γ = 86.221(1)°, V = 2113.95(12) {\AA}3, dx = 4.419 g/cm3, R = 0.0469; [Rh(NH3)5Br][AuBr 4]2·H2O: a = 8.2855(2) {\AA}, b = 15.2881(3) {\AA}, c = 17.4053(4) {\AA}, α = 73.015(1)°, β = 88.913(1)°, γ = 86.267(1)°, V = 2104.08(8) {\AA}3, dx = 4.165 g/sm3, R = 0.0480. The crystal structure of [Ir(NH3)5Br]Br2 is determined. The compound crystallizes in the orthorhombic system, Pnma space group, Z = 4. Crystallographic characteristics: a = 13.8521(3) {\AA}, b = 10.8570(2) {\AA}, c = 6.9908(1) {\AA}, V = 1049.31(3) {\AA}3, d x = 3.273 g/cm3, R = 0.0127.",

keywords = "Double complex salts, Gold, Iridium, Rhodium, Single crystal X-ray diffraction",

author = "Plyusnin, {P. E.} and Semitut, {E. Yu} and Baidina, {I. A.} and Korenev, {S. V.}",

year = "2011",

month = apr,

doi = "10.1134/S002247661102020X",

language = "English",

volume = "52",

pages = "383--388",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "2",

}

TY - JOUR

T1 - Crystal structures of new double complex salts [M(NH3) 5Br][AuBr4]2·H2O, where M = Ir, Rh and complex salt [Ir(NH3)5Br]Br2

AU - Plyusnin, P. E.

AU - Semitut, E. Yu

AU - Baidina, I. A.

AU - Korenev, S. V.

PY - 2011/4

Y1 - 2011/4

N2 - The crystal structures of double complex salts [M(NH3) 5Br][AuBr4]2·H2O (M = Ir, Rh) are determined by single crystal XRD. The compounds crystallize in the triclinic system, P-1 space group, Z = 4. Crystallographic characteristics: [Ir(NH3)5Br][AuBr4]2·H 2O: a = 8.2982(3) Å, b = 15.3045(4) Å, c = 17.4378(6) Å, α = 73.064(1)°, β = 88.938(1)°, γ = 86.221(1)°, V = 2113.95(12) Å3, dx = 4.419 g/cm3, R = 0.0469; [Rh(NH3)5Br][AuBr 4]2·H2O: a = 8.2855(2) Å, b = 15.2881(3) Å, c = 17.4053(4) Å, α = 73.015(1)°, β = 88.913(1)°, γ = 86.267(1)°, V = 2104.08(8) Å3, dx = 4.165 g/sm3, R = 0.0480. The crystal structure of [Ir(NH3)5Br]Br2 is determined. The compound crystallizes in the orthorhombic system, Pnma space group, Z = 4. Crystallographic characteristics: a = 13.8521(3) Å, b = 10.8570(2) Å, c = 6.9908(1) Å, V = 1049.31(3) Å3, d x = 3.273 g/cm3, R = 0.0127.

AB - The crystal structures of double complex salts [M(NH3) 5Br][AuBr4]2·H2O (M = Ir, Rh) are determined by single crystal XRD. The compounds crystallize in the triclinic system, P-1 space group, Z = 4. Crystallographic characteristics: [Ir(NH3)5Br][AuBr4]2·H 2O: a = 8.2982(3) Å, b = 15.3045(4) Å, c = 17.4378(6) Å, α = 73.064(1)°, β = 88.938(1)°, γ = 86.221(1)°, V = 2113.95(12) Å3, dx = 4.419 g/cm3, R = 0.0469; [Rh(NH3)5Br][AuBr 4]2·H2O: a = 8.2855(2) Å, b = 15.2881(3) Å, c = 17.4053(4) Å, α = 73.015(1)°, β = 88.913(1)°, γ = 86.267(1)°, V = 2104.08(8) Å3, dx = 4.165 g/sm3, R = 0.0480. The crystal structure of [Ir(NH3)5Br]Br2 is determined. The compound crystallizes in the orthorhombic system, Pnma space group, Z = 4. Crystallographic characteristics: a = 13.8521(3) Å, b = 10.8570(2) Å, c = 6.9908(1) Å, V = 1049.31(3) Å3, d x = 3.273 g/cm3, R = 0.0127.

KW - Double complex salts

KW - Gold

KW - Iridium

KW - Rhodium

KW - Single crystal X-ray diffraction

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U2 - 10.1134/S002247661102020X

DO - 10.1134/S002247661102020X

M3 - Article

AN - SCOPUS:80054737380

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SP - 383

EP - 388

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

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