Crystal structure of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L = 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en)

E. A. Bykova, S. P. Khranenko, E. Yu Semitut, S. A. Gromilov

Результат исследований: Материалы для журналаСтатья

4 Цитирования (Scopus)

Выдержка

The crystal structures of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L is 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO 3)(ReO 4) is completed to a distorted octahedron by two oxygen atoms: Cu⋯O (ReO 4 - ) 2.393 Å and Cu⋯O (NO 3 - ) 2.685 Å, and that in [CuL](ReO 4) 2, by Cu⋯O(ReO 4 - ) 2.468 Å and 2.697 Å. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.

Язык оригиналаАнглийский
Страницы (с-по)138-144
Число страниц7
ЖурналJournal of Structural Chemistry
Том53
Номер выпуска1
DOI
СостояниеОпубликовано - фев 2012
Опубликовано для внешнего пользованияДа

Отпечаток

metal powder
coherent scattering
oxygen atoms
Crystal structure
Coherent scattering
salts
atmospheres
copper
Atoms
Thermolysis
crystal structure
Powder metals
hydrogen
products
atoms
Copper
Hydrogen
Salts
Oxygen

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Цитировать

Crystal structure of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L = 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en). / Bykova, E. A.; Khranenko, S. P.; Semitut, E. Yu; Gromilov, S. A.

В: Journal of Structural Chemistry, Том 53, № 1, 02.2012, стр. 138-144.

Результат исследований: Материалы для журналаСтатья

Bykova, E. A. ; Khranenko, S. P. ; Semitut, E. Yu ; Gromilov, S. A. / Crystal structure of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L = 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en). В: Journal of Structural Chemistry. 2012 ; Том 53, № 1. стр. 138-144.
@article{8894273fd83a45f195c7e1769b700bd6,
title = "Crystal structure of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L = 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en)",
abstract = "The crystal structures of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L is 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO 3)(ReO 4) is completed to a distorted octahedron by two oxygen atoms: Cu⋯O (ReO 4 - ) 2.393 {\AA} and Cu⋯O (NO 3 - ) 2.685 {\AA}, and that in [CuL](ReO 4) 2, by Cu⋯O(ReO 4 - ) 2.468 {\AA} and 2.697 {\AA}. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.",
keywords = "copper, crystal chemistry, rhenium, single crystal X-ray diffraction, thermal studies",
author = "Bykova, {E. A.} and Khranenko, {S. P.} and Semitut, {E. Yu} and Gromilov, {S. A.}",
year = "2012",
month = "2",
doi = "10.1134/S0022476612010180",
language = "English",
volume = "53",
pages = "138--144",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "1",

}

TY - JOUR

T1 - Crystal structure of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L = 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en)

AU - Bykova, E. A.

AU - Khranenko, S. P.

AU - Semitut, E. Yu

AU - Gromilov, S. A.

PY - 2012/2

Y1 - 2012/2

N2 - The crystal structures of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L is 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO 3)(ReO 4) is completed to a distorted octahedron by two oxygen atoms: Cu⋯O (ReO 4 - ) 2.393 Å and Cu⋯O (NO 3 - ) 2.685 Å, and that in [CuL](ReO 4) 2, by Cu⋯O(ReO 4 - ) 2.468 Å and 2.697 Å. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.

AB - The crystal structures of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L is 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO 3)(ReO 4) is completed to a distorted octahedron by two oxygen atoms: Cu⋯O (ReO 4 - ) 2.393 Å and Cu⋯O (NO 3 - ) 2.685 Å, and that in [CuL](ReO 4) 2, by Cu⋯O(ReO 4 - ) 2.468 Å and 2.697 Å. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.

KW - copper

KW - crystal chemistry

KW - rhenium

KW - single crystal X-ray diffraction

KW - thermal studies

UR - http://www.scopus.com/inward/record.url?scp=84859123328&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84859123328&partnerID=8YFLogxK

U2 - 10.1134/S0022476612010180

DO - 10.1134/S0022476612010180

M3 - Article

AN - SCOPUS:84859123328

VL - 53

SP - 138

EP - 144

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 1

ER -