Crystal structure of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L = 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en)

E. A. Bykova, S. P. Khranenko, E. Yu Semitut, S. A. Gromilov

Результат исследования: Материалы для журналаСтатья

5 Цитирования (Scopus)

Аннотация

The crystal structures of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L is 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO 3)(ReO 4) is completed to a distorted octahedron by two oxygen atoms: Cu⋯O (ReO 4 - ) 2.393 Å and Cu⋯O (NO 3 - ) 2.685 Å, and that in [CuL](ReO 4) 2, by Cu⋯O(ReO 4 - ) 2.468 Å and 2.697 Å. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.

Язык оригиналаАнглийский
Страницы (с... по...)138-144
Количество страниц7
ЖурналJournal of Structural Chemistry
Том53
Номер выпуска1
DOI
Статус публикацииОпубликовано - фев 2012
Опубликовано для внешнего пользованияДа

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ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

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