Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane: Synthesis, spectroscopic study, and crystal structure

E. V. Lider, E. V. Peresypkina, L. G. Lavrenova, O. L. Krivenko, E. G. Boguslavskii, A. I. Smolentsev, L. A. Sheludyakova, S. F. Vasilevskii

Результат исследования: Материалы для журналаСтатья

3 Цитирования (Scopus)

Аннотация

New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.

Язык оригиналаАнглийский
Страницы (с... по...)433-444
Количество страниц12
ЖурналRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том35
Номер выпуска6
DOI
Статус публикацииОпубликовано - 1 июн 2009
Опубликовано для внешнего пользованияДа

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ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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