Color centers in heavily irradiated CsI(Tl) crystals

V. Yakovlev, A. Meleshko, L. Trefilova

Результат исследований: Материалы для журналаСтатья

8 Цитирования (Scopus)

Аннотация

The absorption and luminescence properties of CsI(Tl) crystals colored by irradiation are studied by the method of the time-resolved spectroscopy. The scheme of the electron transitions in CsI(Tl) crystal is suggested to explain the appearance of the color centers under exposure to the near-UV light. It is established that either of the two types activator color centers holds the charge carrier with opposite sign. The model of the hole Tl2+vc - activator color center is suggested. According to the model the positive charge of Tl2+ ion is compensated by the negative charge of a close cation vacancy vc -. The color center emission reveals in the cathode-luminescence spectrum of the colored CsI(Tl) crystal. The high-dose irradiation of CsI(Tl) crystal results in the reduction of the decay time of the near-thallium self-trapped excitons (STE) emission. The decay kinetics of Tl2+vc - emission contains the time components typical for the decay kinetics of near-thallium STE emission. The reason of the observed effects is the energy transfer from the near-thallium STE excitons to the color centers via the inductive-resonant mechanism.

Язык оригиналаАнглийский
Страницы (с-по)1447-1453
Число страниц7
ЖурналJournal of Luminescence
Том128
Номер выпуска9
DOI
СостояниеОпубликовано - сен 2008

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Atomic and Molecular Physics, and Optics

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