Click chemistry in materials synthesis. 1. Adhesive polymers from copper-catalyzed azide-alkyne cycloaddition

David D. Díaz, Sreenivas Punna, Philipp Holzer, Andrew K. Mcpherson, K. Barry Sharpless, Valery V. Fokin, M. G. Finn

Результат исследований: Материалы для журналаСтатья

389 Цитирования (Scopus)

Аннотация

The copper(I)-catalyzed cycloaddition reaction between azides and alkynes has been employed to make metal-adhesive materials. Copper and brass surfaces supply the necessary catalytic Cu ions, and thus the polymerization process occurs selectively on these metals in the absence of added catalysts. Alternatively, copper compounds can be added to monomer mixtures and then introduced to reducing metal surfaces such as zinc to initiate polymerization. The resulting materials were found to possess comparable or superior adhesive strength to standard commercial glues, and structure-activity correlations have identified several important properties of the monomers.

Язык оригиналаАнглийский
Страницы (с-по)4392-4403
Число страниц12
ЖурналJournal of Polymer Science, Part A: Polymer Chemistry
Том42
Номер выпуска17
DOI
СостояниеОпубликовано - 1 сен 2004
Опубликовано для внешнего пользованияДа

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

Fingerprint Подробные сведения о темах исследования «Click chemistry in materials synthesis. 1. Adhesive polymers from copper-catalyzed azide-alkyne cycloaddition». Вместе они формируют уникальный семантический отпечаток (fingerprint).

  • Цитировать

    Díaz, D. D., Punna, S., Holzer, P., Mcpherson, A. K., Sharpless, K. B., Fokin, V. V., & Finn, M. G. (2004). Click chemistry in materials synthesis. 1. Adhesive polymers from copper-catalyzed azide-alkyne cycloaddition. Journal of Polymer Science, Part A: Polymer Chemistry, 42(17), 4392-4403. https://doi.org/10.1002/pola.20330