Chemical and photochemical water oxidation catalyzed by novel ruthenium complexes comprising a negatively charged NCNHCO ligand

Wei Su, Hussein A. Younus, Kui Zhou, Zafar A.K. Khattak, Somboon Chaemcheun, Cheng Chen, Francis Verpoort

Результат исследований: Материалы для журналаСтатья

10 Цитирования (Scopus)

Аннотация

Incorporation of negatively charged moieties into complexes is a promising strategy to develop water oxidation catalysts with high stability and low over-potentials. We reported here the synthesis of a novel pincer-type ligand precursor, 1-(pyridin-2-ylmethyl)-3-methylcarboxylate-imidazolium (1). Deprotonation of C2-H of 1 resulted in formation of NCNHCO, a negatively charged asymmetric N-heterocyclic carbene (NHC). Complexes [Ru(NCNHCO)(terpy)]+ (2) and RuCl(NCNHCO)(DMSO)(pic) (3) were prepared and capable of decomposing water chemically and photo-chemically. Under acidic conditions, 4-picoline/H2O exchange in 3 was detected by UV-vis and 1H NMR, forming the corresponding Ru-aqua complex. In a typical three-component light-induced water oxidation, a turnover number of 273 was attained employing 3, which demonstrated catalytic ability comparable to those state-of-the-art catalysts.

Язык оригиналаАнглийский
Страницы (с-по)387-395
Число страниц9
ЖурналCatalysis Science and Technology
Том7
Номер выпуска2
DOI
СостояниеОпубликовано - 1 янв 2017

ASJC Scopus subject areas

  • Catalysis

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