Chemical and Photochemical Water Oxidation by [RuCl(NCNHCO)(DMSO)(py)]-Type Complexes

Wei Su, Hussein A. Younus, Somboon Chaemchuen, Cheng Chen, Francis Verpoort

Результат исследований: Материалы для журналаСтатья

2 Цитирования (Scopus)

Выдержка

In this work, the effects of substitutions in the backbone of imidazolylidene and axial ligands on the reactivity and stability of water-oxidation catalysts were investigated. Three pincer-type asymmetric imidazolium salts NCNHCO, NCNHC-4BrO, and NCNHC-BO (NHC: N-heterocyclic carbene), of which the donating ability of the corresponding imidazolylidene decreases in the same sequence, were prepared. Their application in metalation afforded the corresponding Ru complexes 1 a, 1 b, 2, and 3. It was found that the complexes incorporating the stronger donor displayed lower potential for each redox couple and longer lifetimes, but relatively low reaction rates. Under acidic conditions, water oxidation driven by cerium ammonium nitrate resulted in turnover numbers (TONs) of 2322, 1728, 1928, and 2208 for 1 a, 1 b, 2, and 3, respectively. Complex 2 exhibited a good match of reactivity and stability with a TON of 136 in a typical three-component photocatalysis. Importantly, NHCs could be another powerful tool for tuning the reactivity and stability of water-oxidation catalysts, in addition to substituted pyridines. Rational orchestration of modified NHCs and pyridines could eventually result in water-oxidation catalysts exhibiting appreciable effectiveness and considerable robustness.

Язык оригиналаАнглийский
Страницы (с-по)2565-2573
Число страниц9
ЖурналChemCatChem
Том9
Номер выпуска13
DOI
СостояниеОпубликовано - 7 июл 2017

Отпечаток

Dimethyl Sulfoxide
Pyridines
Oxidation
oxidation
reactivity
Water
catalysts
Pyridine
water
Catalysts
pyridines
Cerium
ammonium nitrates
Photocatalysis
carbenes
cerium
Reaction rates
Nitrates
reaction kinetics
Substitution reactions

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Цитировать

Chemical and Photochemical Water Oxidation by [RuCl(NCNHCO)(DMSO)(py)]-Type Complexes. / Su, Wei; Younus, Hussein A.; Chaemchuen, Somboon; Chen, Cheng; Verpoort, Francis.

В: ChemCatChem, Том 9, № 13, 07.07.2017, стр. 2565-2573.

Результат исследований: Материалы для журналаСтатья

Su, Wei ; Younus, Hussein A. ; Chaemchuen, Somboon ; Chen, Cheng ; Verpoort, Francis. / Chemical and Photochemical Water Oxidation by [RuCl(NCNHCO)(DMSO)(py)]-Type Complexes. В: ChemCatChem. 2017 ; Том 9, № 13. стр. 2565-2573.
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