Catalytic Cycloisomerization–Fluorination Sequence of N-Propargyl Amides by Iodoarene/HF⋅Pyridine/Selectfluor Systems

Naoki Asari, Yusuke Takemoto, Yukino Shinomoto, Takuma Yagyu, Akira Yoshimura, Viktor V. Zhdankin, Akio Saito

Результат исследований: Материалы для журналаСтатья

9 Цитирования (Scopus)

Выдержка

As a first example of metal-free and catalytic fluorinative transformations of alkynes, we developed a cycloisomerization–fluorination sequence of N-propargyl amides catalyzed by an iodine(III) species. The iodine(III) catalyst is in situ generated from iodoarene as a precatalyst with Selectfluor as a fluorinating oxidant in the presence of HF⋅pyridine.

Язык оригиналаАнглийский
Страницы (с-по)1314-1317
Число страниц4
ЖурналAsian Journal of Organic Chemistry
Том5
Номер выпуска11
DOI
СостояниеОпубликовано - 1 ноя 2016
Опубликовано для внешнего пользованияДа

Отпечаток

Amides
Iodine
Alkynes
Oxidants
Metals
Catalysts
selectfluor
N-propargyl

ASJC Scopus subject areas

  • Organic Chemistry

Цитировать

Catalytic Cycloisomerization–Fluorination Sequence of N-Propargyl Amides by Iodoarene/HF⋅Pyridine/Selectfluor Systems. / Asari, Naoki; Takemoto, Yusuke; Shinomoto, Yukino; Yagyu, Takuma; Yoshimura, Akira; Zhdankin, Viktor V.; Saito, Akio.

В: Asian Journal of Organic Chemistry, Том 5, № 11, 01.11.2016, стр. 1314-1317.

Результат исследований: Материалы для журналаСтатья

Asari, Naoki ; Takemoto, Yusuke ; Shinomoto, Yukino ; Yagyu, Takuma ; Yoshimura, Akira ; Zhdankin, Viktor V. ; Saito, Akio. / Catalytic Cycloisomerization–Fluorination Sequence of N-Propargyl Amides by Iodoarene/HF⋅Pyridine/Selectfluor Systems. В: Asian Journal of Organic Chemistry. 2016 ; Том 5, № 11. стр. 1314-1317.
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AU - Takemoto, Yusuke

AU - Shinomoto, Yukino

AU - Yagyu, Takuma

AU - Yoshimura, Akira

AU - Zhdankin, Viktor V.

AU - Saito, Akio

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