Catalytic behavior of bimetallic Ni–Fe systems in the decomposition of 1,2-dichloroethane. Effect of iron doping and preparation route

Yuri I. Bauman, Nikolay V. Kutaev, Pavel E. Plyusnin, Ilya V. Mishakov, Yury V. Shubin, Aleksey A. Vedyagin, Roman A. Buyanov

Результат исследований: Материалы для журналаСтатья

5 Цитирования (Scopus)

Выдержка

Model bimetallic Ni–Fe catalysts were prepared by coprecipitation from aqueous solutions of nitrates and by mechanical alloying of metal powders. Pure nickel samples subjected to the similar procedures were used as references. The obtained samples were characterized by scanning electron microscopy and X-ray diffraction analysis. Catalytic chemical vapor deposition of 1,2-dichloroethane over the catalysts was studied in a quartz flow reactor equipped with a McBain balance. It was shown that in the case of coprecipitation followed by reduction, Ni–Fe solid solution is formed within the studied range of Fe loading (1–10 wt%). Activation times of 6 min and longer are required to obtain this solid solution by the mechanical alloying method. Despite the known catalytic activity of nickel and iron in hydrocarbon decomposition in accordance with carbide cycle mechanism, iron doping was found to worsen the behavior of nickel in the studied reaction where chlorinated alkane plays a role of substrate to be decomposed. The formation of thermodynamically more stable iron chloride in relation to nickel chloride leads to deactivation of the catalyst and deceleration of the overall process.

Язык оригиналаАнглийский
Страницы (с-по)1-11
Число страниц11
ЖурналReaction Kinetics, Mechanisms and Catalysis
Том121
Номер выпуска2
DOI
СостояниеПринято/в печати - 10 апр 2017

Отпечаток

Nickel
Iron
routes
Mechanical alloying
Doping (additives)
nickel
Coprecipitation
Decomposition
decomposition
iron
preparation
Catalysts
Solid solutions
catalysts
alloying
Quartz
Alkanes
solid solutions
Powder metals
iron chlorides

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Цитировать

Catalytic behavior of bimetallic Ni–Fe systems in the decomposition of 1,2-dichloroethane. Effect of iron doping and preparation route. / Bauman, Yuri I.; Kutaev, Nikolay V.; Plyusnin, Pavel E.; Mishakov, Ilya V.; Shubin, Yury V.; Vedyagin, Aleksey A.; Buyanov, Roman A.

В: Reaction Kinetics, Mechanisms and Catalysis, Том 121, № 2, 10.04.2017, стр. 1-11.

Результат исследований: Материалы для журналаСтатья

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abstract = "Model bimetallic Ni–Fe catalysts were prepared by coprecipitation from aqueous solutions of nitrates and by mechanical alloying of metal powders. Pure nickel samples subjected to the similar procedures were used as references. The obtained samples were characterized by scanning electron microscopy and X-ray diffraction analysis. Catalytic chemical vapor deposition of 1,2-dichloroethane over the catalysts was studied in a quartz flow reactor equipped with a McBain balance. It was shown that in the case of coprecipitation followed by reduction, Ni–Fe solid solution is formed within the studied range of Fe loading (1–10 wt{\%}). Activation times of 6 min and longer are required to obtain this solid solution by the mechanical alloying method. Despite the known catalytic activity of nickel and iron in hydrocarbon decomposition in accordance with carbide cycle mechanism, iron doping was found to worsen the behavior of nickel in the studied reaction where chlorinated alkane plays a role of substrate to be decomposed. The formation of thermodynamically more stable iron chloride in relation to nickel chloride leads to deactivation of the catalyst and deceleration of the overall process.",
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AU - Bauman, Yuri I.

AU - Kutaev, Nikolay V.

AU - Plyusnin, Pavel E.

AU - Mishakov, Ilya V.

AU - Shubin, Yury V.

AU - Vedyagin, Aleksey A.

AU - Buyanov, Roman A.

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N2 - Model bimetallic Ni–Fe catalysts were prepared by coprecipitation from aqueous solutions of nitrates and by mechanical alloying of metal powders. Pure nickel samples subjected to the similar procedures were used as references. The obtained samples were characterized by scanning electron microscopy and X-ray diffraction analysis. Catalytic chemical vapor deposition of 1,2-dichloroethane over the catalysts was studied in a quartz flow reactor equipped with a McBain balance. It was shown that in the case of coprecipitation followed by reduction, Ni–Fe solid solution is formed within the studied range of Fe loading (1–10 wt%). Activation times of 6 min and longer are required to obtain this solid solution by the mechanical alloying method. Despite the known catalytic activity of nickel and iron in hydrocarbon decomposition in accordance with carbide cycle mechanism, iron doping was found to worsen the behavior of nickel in the studied reaction where chlorinated alkane plays a role of substrate to be decomposed. The formation of thermodynamically more stable iron chloride in relation to nickel chloride leads to deactivation of the catalyst and deceleration of the overall process.

AB - Model bimetallic Ni–Fe catalysts were prepared by coprecipitation from aqueous solutions of nitrates and by mechanical alloying of metal powders. Pure nickel samples subjected to the similar procedures were used as references. The obtained samples were characterized by scanning electron microscopy and X-ray diffraction analysis. Catalytic chemical vapor deposition of 1,2-dichloroethane over the catalysts was studied in a quartz flow reactor equipped with a McBain balance. It was shown that in the case of coprecipitation followed by reduction, Ni–Fe solid solution is formed within the studied range of Fe loading (1–10 wt%). Activation times of 6 min and longer are required to obtain this solid solution by the mechanical alloying method. Despite the known catalytic activity of nickel and iron in hydrocarbon decomposition in accordance with carbide cycle mechanism, iron doping was found to worsen the behavior of nickel in the studied reaction where chlorinated alkane plays a role of substrate to be decomposed. The formation of thermodynamically more stable iron chloride in relation to nickel chloride leads to deactivation of the catalyst and deceleration of the overall process.

KW - 1,2-Dichlorethane

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KW - Carbon nanofibers

KW - Decomposition

KW - Metal dusting

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