Br2F7- and Br3F10-: peculiar anions showing mu(2)- and mu(3)-bridging F-atoms: Peculiar anions showing μ2- and μ3-bridging F-atoms

S. I. Ivlev, A. J. Karttunen, R. V. Ostvald, F. Kraus

Результат исследований: Материалы для журналаСтатьярецензирование

16 Цитирования (Scopus)

Аннотация

RbCl and CsCl react with BrF3 yielding the corresponding decafluoridotribromates(iii), MBr3F10 (M = Rb, Cs), which were structurally characterized for the first time. The Br3F10 - anion is surprisingly not linear but contains a μ3-bridging fluorine atom and seems to be the first example of μ3-F bridging of Br atoms. The compounds are highly reactive and cannot be handled in glassware. As for the tetrafluoridobromates themselves, they are powerful oxidizers and thus suitable for the dry-chemical recycling of precious metals and additionally feature a significantly higher BrF3 content.

Язык оригиналаАнглийский
Страницы (с-по)12040-12043
Число страниц4
ЖурналChemical Communications
Том52
Номер выпуска81
DOI
СостояниеОпубликовано - 2016

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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