Aryl Germanes as Ligands for Transition Polymetallic Complexes

Synthesis, Structure, and Properties

Kirill V. Zaitsev, Kevin Lam, Oleg Kh Poleshchuk, Stanislav I. Bezzubov, Andrei V. Churakov

    Результат исследований: Материалы для журналаСтатья

    1 цитирование (Scopus)

    Выдержка

    A series of new carbonyl dichromium complexes bearing aryl germanes as ligands were prepared using improved approaches. The thermal reaction of Cr(CO)6 (1) with Me3GeGePh3 (3) led to the formation of Me3GeGePh[(η6-C6H5)Cr(CO)3]2 (3a). The lithiation of [(η6-C6H6)Cr(CO)3] (2) with nBuLi followed by the addition of Me2GeCl2 (4) or ClGeMe2GeMe2Cl (5) gave Me2Ge[(η6-C6H5)Cr(CO)3]2 (4a) and [(OC)3Cr(η6-C6H5)]GeMe2GeMe2[(η6-C6H5)Cr(CO)3] (5a), respectively. The molecular structures of 3a and 4a, in their crystal forms, were studied by X-ray diffraction analysis. The crystals of oligogermane 3a have shown to undergo a fully reversible phase transition at 160 K without any sign of decomposition. The complexes synthesized were also studied by multinuclear NMR, IR and UV/Vis spectroscopy, DFT calculations and electrochemistry. The presence of a Cr(CO)3 group in a range of oligogermanes has shown to impact on the physical and chemical properties of the compounds.

    Язык оригиналаАнглийский
    Страницы (с-по)2750-2760
    Число страниц11
    ЖурналEuropean Journal of Inorganic Chemistry
    Том2019
    Номер выпуска22
    DOI
    СостояниеОпубликовано - 16 июн 2019

    Отпечаток

    Carbon Monoxide
    Ligands
    Bearings (structural)
    Crystals
    Electrochemistry
    Ultraviolet spectroscopy
    Discrete Fourier transforms
    Chemical properties
    X ray diffraction analysis
    Molecular structure
    Physical properties
    Phase transitions
    Nuclear magnetic resonance
    Decomposition

    ASJC Scopus subject areas

    • Inorganic Chemistry

    Цитировать

    Aryl Germanes as Ligands for Transition Polymetallic Complexes : Synthesis, Structure, and Properties. / Zaitsev, Kirill V.; Lam, Kevin; Poleshchuk, Oleg Kh; Bezzubov, Stanislav I.; Churakov, Andrei V.

    В: European Journal of Inorganic Chemistry, Том 2019, № 22, 16.06.2019, стр. 2750-2760.

    Результат исследований: Материалы для журналаСтатья

    Zaitsev, KV, Lam, K, Poleshchuk, OK, Bezzubov, SI & Churakov, AV 2019, 'Aryl Germanes as Ligands for Transition Polymetallic Complexes: Synthesis, Structure, and Properties', European Journal of Inorganic Chemistry, том. 2019, № 22, стр. 2750-2760. https://doi.org/10.1002/ejic.201900316
    Zaitsev, Kirill V. ; Lam, Kevin ; Poleshchuk, Oleg Kh ; Bezzubov, Stanislav I. ; Churakov, Andrei V. / Aryl Germanes as Ligands for Transition Polymetallic Complexes : Synthesis, Structure, and Properties. В: European Journal of Inorganic Chemistry. 2019 ; Том 2019, № 22. стр. 2750-2760.
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    abstract = "A series of new carbonyl dichromium complexes bearing aryl germanes as ligands were prepared using improved approaches. The thermal reaction of Cr(CO)6 (1) with Me3GeGePh3 (3) led to the formation of Me3GeGePh[(η6-C6H5)Cr(CO)3]2 (3a). The lithiation of [(η6-C6H6)Cr(CO)3] (2) with nBuLi followed by the addition of Me2GeCl2 (4) or ClGeMe2GeMe2Cl (5) gave Me2Ge[(η6-C6H5)Cr(CO)3]2 (4a) and [(OC)3Cr(η6-C6H5)]GeMe2GeMe2[(η6-C6H5)Cr(CO)3] (5a), respectively. The molecular structures of 3a and 4a, in their crystal forms, were studied by X-ray diffraction analysis. The crystals of oligogermane 3a have shown to undergo a fully reversible phase transition at 160 K without any sign of decomposition. The complexes synthesized were also studied by multinuclear NMR, IR and UV/Vis spectroscopy, DFT calculations and electrochemistry. The presence of a Cr(CO)3 group in a range of oligogermanes has shown to impact on the physical and chemical properties of the compounds.",
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    AU - Bezzubov, Stanislav I.

    AU - Churakov, Andrei V.

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    AB - A series of new carbonyl dichromium complexes bearing aryl germanes as ligands were prepared using improved approaches. The thermal reaction of Cr(CO)6 (1) with Me3GeGePh3 (3) led to the formation of Me3GeGePh[(η6-C6H5)Cr(CO)3]2 (3a). The lithiation of [(η6-C6H6)Cr(CO)3] (2) with nBuLi followed by the addition of Me2GeCl2 (4) or ClGeMe2GeMe2Cl (5) gave Me2Ge[(η6-C6H5)Cr(CO)3]2 (4a) and [(OC)3Cr(η6-C6H5)]GeMe2GeMe2[(η6-C6H5)Cr(CO)3] (5a), respectively. The molecular structures of 3a and 4a, in their crystal forms, were studied by X-ray diffraction analysis. The crystals of oligogermane 3a have shown to undergo a fully reversible phase transition at 160 K without any sign of decomposition. The complexes synthesized were also studied by multinuclear NMR, IR and UV/Vis spectroscopy, DFT calculations and electrochemistry. The presence of a Cr(CO)3 group in a range of oligogermanes has shown to impact on the physical and chemical properties of the compounds.

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    KW - Reversible phase transition

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