Antifrictional nanocomposites based on chemically modified UHMWPE. Part 3. Comparison of modification effect of compatibilizers on mechanical and tribotechnical properties

S. V. Panin, L. A. Kornienko, S. Piriyaon, N. Sonjaitham, L. R. Ivanova, S. V. Shilko, Yu M. Pleskachevskii, V. M. Orlov

Результат исследований: Материалы для журналаСтатья

4 Цитирования (Scopus)

Выдержка

Two compatibilizers-vinyltrimethoxysilane (VTMS) and maleic anhydride (SMA)-are subjected to comparative analysis in respect to their effect on the mechanical and tribological properties of the composites based on chemically modified UHMWPE. The methods of IR spectroscopy, scanning differential calorimetry, and electronic microscopy are used to study the supermolecular structure of nanocomposites on the base of UHMWPE block-copolymer + 10% UHMWPE-g-VTMS. The mechanical and tribotechnical properties of these nanocomposites are further compared to those of the nanocomposites based on UHMWPE + 10% HDPE-g-SMA. It is shown that the nanocomposites based on block-copolymers with the mentioned compatibilizers have similar (spherulitic) structure and roughly equal wear resistance, being close to those of the composites based on the non-modified polymer. The wear resistance of the nanocomposites on the base of UHMWPE depends on whether the fillers are present and distributed evenly in the matrix. This defines the crystallization conditions and, as a consequence, the type of the formed supermolecular structure.

Язык оригиналаАнглийский
Страницы (с-по)47-52
Число страниц6
ЖурналJournal of Friction and Wear
Том33
Номер выпуска1
DOI
СостояниеОпубликовано - фев 2012

Отпечаток

Ultrahigh molecular weight polyethylenes
Compatibilizers
Nanocomposites
Maleic Anhydrides
Maleic anhydride
Block copolymers
Wear resistance
Composite materials
Polyethylene
High density polyethylenes
Crystallization
Fillers
Differential scanning calorimetry
Infrared spectroscopy
Microscopic examination
Polymers
ultra-high molecular weight polyethylene

ASJC Scopus subject areas

  • Mechanics of Materials
  • Surfaces, Coatings and Films

Цитировать

Antifrictional nanocomposites based on chemically modified UHMWPE. Part 3. Comparison of modification effect of compatibilizers on mechanical and tribotechnical properties. / Panin, S. V.; Kornienko, L. A.; Piriyaon, S.; Sonjaitham, N.; Ivanova, L. R.; Shilko, S. V.; Pleskachevskii, Yu M.; Orlov, V. M.

В: Journal of Friction and Wear, Том 33, № 1, 02.2012, стр. 47-52.

Результат исследований: Материалы для журналаСтатья

Panin, S. V. ; Kornienko, L. A. ; Piriyaon, S. ; Sonjaitham, N. ; Ivanova, L. R. ; Shilko, S. V. ; Pleskachevskii, Yu M. ; Orlov, V. M. / Antifrictional nanocomposites based on chemically modified UHMWPE. Part 3. Comparison of modification effect of compatibilizers on mechanical and tribotechnical properties. В: Journal of Friction and Wear. 2012 ; Том 33, № 1. стр. 47-52.
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abstract = "Two compatibilizers-vinyltrimethoxysilane (VTMS) and maleic anhydride (SMA)-are subjected to comparative analysis in respect to their effect on the mechanical and tribological properties of the composites based on chemically modified UHMWPE. The methods of IR spectroscopy, scanning differential calorimetry, and electronic microscopy are used to study the supermolecular structure of nanocomposites on the base of UHMWPE block-copolymer + 10{\%} UHMWPE-g-VTMS. The mechanical and tribotechnical properties of these nanocomposites are further compared to those of the nanocomposites based on UHMWPE + 10{\%} HDPE-g-SMA. It is shown that the nanocomposites based on block-copolymers with the mentioned compatibilizers have similar (spherulitic) structure and roughly equal wear resistance, being close to those of the composites based on the non-modified polymer. The wear resistance of the nanocomposites on the base of UHMWPE depends on whether the fillers are present and distributed evenly in the matrix. This defines the crystallization conditions and, as a consequence, the type of the formed supermolecular structure.",
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AU - Kornienko, L. A.

AU - Piriyaon, S.

AU - Sonjaitham, N.

AU - Ivanova, L. R.

AU - Shilko, S. V.

AU - Pleskachevskii, Yu M.

AU - Orlov, V. M.

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AB - Two compatibilizers-vinyltrimethoxysilane (VTMS) and maleic anhydride (SMA)-are subjected to comparative analysis in respect to their effect on the mechanical and tribological properties of the composites based on chemically modified UHMWPE. The methods of IR spectroscopy, scanning differential calorimetry, and electronic microscopy are used to study the supermolecular structure of nanocomposites on the base of UHMWPE block-copolymer + 10% UHMWPE-g-VTMS. The mechanical and tribotechnical properties of these nanocomposites are further compared to those of the nanocomposites based on UHMWPE + 10% HDPE-g-SMA. It is shown that the nanocomposites based on block-copolymers with the mentioned compatibilizers have similar (spherulitic) structure and roughly equal wear resistance, being close to those of the composites based on the non-modified polymer. The wear resistance of the nanocomposites on the base of UHMWPE depends on whether the fillers are present and distributed evenly in the matrix. This defines the crystallization conditions and, as a consequence, the type of the formed supermolecular structure.

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KW - wear resistance

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