Analytical pyrolysis of insoluble products obtained by thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field

Vladimir R. Antipenko, Andrey A. Grin'Ko, Anatoly K. Golovko, Vasily N. Melenevskiy

Результат исследований: Материалы для книги/типы отчетовМатериалы для конференции

Аннотация

Presented are the results on the study of insoluble products obtained at autoclave thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field in an argon atmosphere at 160-650°C. A high yielded chloroform-insoluble thermolysis product obtained from the resins of heavy high-sulfur oil at 250°C significantly differs from products obtained from resins and asphaltenes at 450 and 650°C but according to the results of Rock Eval and 'on-line' flash pyrolysis (600°C, 20 s), and elemental analysis it is similar to 'asphaltene-like' substances. Their formation is probably due to the cleavage at 250°C of the most labile S-S or C-S bonds in the resin molecules followed by generation and recombination of macroradicals. The thermal destruction of these substances at higher temperatures (450 and 650°C) is accompanied by the formation of more carbonized coke-like products.

Язык оригиналаАнглийский
Название основной публикацииProceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures
РедакторыVasily M. Fomin, Victor E. Panin, Sergey G. Psakhie
ИздательAmerican Institute of Physics Inc.
ISBN (электронное издание)9780735417779
DOI
СостояниеОпубликовано - 12 дек 2018
СобытиеInternational Symposium on Hierarchical Materials: Development and Applications for New Technologies and Reliable Structures 2018 - Tomsk, Российская Федерация
Продолжительность: 1 окт 20185 окт 2018

Серия публикаций

НазваниеAIP Conference Proceedings
Том2051
ISSN (печатное издание)0094-243X
ISSN (электронное издание)1551-7616

Конференция

КонференцияInternational Symposium on Hierarchical Materials: Development and Applications for New Technologies and Reliable Structures 2018
СтранаРоссийская Федерация
ГородTomsk
Период1.10.185.10.18

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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  • Цитировать

    Antipenko, V. R., Grin'Ko, A. A., Golovko, A. K., & Melenevskiy, V. N. (2018). Analytical pyrolysis of insoluble products obtained by thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field. В V. M. Fomin, V. E. Panin, & S. G. Psakhie (Ред.), Proceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures [020019] (AIP Conference Proceedings; Том 2051). American Institute of Physics Inc.. https://doi.org/10.1063/1.5083262