An x-ray diffraction study of the reaction products of copper(II) chloride with N1,N2-BIS(5-methylpyridin-2-YL)oxalamide

D. A. Piryazev, A. S. Zhilin, A. I. Smolentsev, A. V. Virovets, S. F. Vasilevskii, L. G. Lavrenova

Результат исследований: Материалы для журналаСтатья

1 Цитирования (Scopus)

Аннотация

Polymeric complexes of [Cu2Cl2L2]∞ copper(I) chloride (1) (L = N1,N2-bis(5-methylpyridin-2- yl)- oxalamide)) and {[Cu2(C2O4)Cl 2L](L)·2H2O}∞ copper(II) chloride (2) are obtained. The complexes are studied by powder and single crystal XRD. It is found that during the reaction of L with copper(II) chloride in the formation of complex 1 copper(II) is reduced to copper(I), while the formation of complex 2 is accompanied by the hydrolysis of the ligand.

Язык оригиналаАнглийский
Страницы (с-по)376-382
Число страниц7
ЖурналJournal of Structural Chemistry
Том52
Номер выпуска2
DOI
СостояниеОпубликовано - 1 янв 2011
Опубликовано для внешнего пользованияДа

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Подробные сведения о темах исследования «An x-ray diffraction study of the reaction products of copper(II) chloride with N<sup>1</sup>,N<sup>2</sup>-BIS(5-methylpyridin-2-YL)oxalamide». Вместе они формируют уникальный семантический отпечаток (fingerprint).

  • Цитировать