Advances in Synthetic Applications of Hypervalent Iodine Compounds

Результат исследований: Материалы для журналаОбзорная статья

744 Цитирования (Scopus)

Аннотация

The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed with emphasis on their synthetic application. Compounds of iodine possess reactivity similar to that of transition metals, but have the advantage of environmental sustainability and efficient utilization of natural resources. These compounds are widely used in organic synthesis as selective oxidants and environmentally friendly reagents. Synthetic uses of hypervalent iodine reagents in halogenation reactions, various oxidations, rearrangements, aminations, C-C bond-forming reactions, and transition metal-catalyzed reactions are summarized and discussed. Recent discovery of hypervalent catalytic systems and recyclable reagents, and the development of new enantioselective reactions using chiral hypervalent iodine compounds represent a particularly important achievement in the field of hypervalent iodine chemistry. One of the goals of this Review is to attract the attention of the scientific community as to the benefits of using hypervalent iodine compounds as an environmentally sustainable alternative to heavy metals.

Язык оригиналаАнглийский
Страницы (с-по)3328-3435
Число страниц108
ЖурналChemical Reviews
Том116
Номер выпуска5
DOI
СостояниеОпубликовано - 9 мар 2016
Опубликовано для внешнего пользованияДа

ASJC Scopus subject areas

  • Chemistry(all)

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