A New Rotational Study of the Ground Vibrational State of CHD₃

O. N. Ulenikov, G. A. Onopenko, N. E. Tyabaeva, S. Alanko, M. Koivusaari, R. Anttila

Исследовательская школа физики высокоэнергетических процессов

Результат исследований: Материалы для журнала › Статья › рецензирование

Аннотация

A careful rotational analysis of the ground vibrational state of the CHD₃ molecule is made on the basis of the ground state combination differences method using, as the initial information, transitions from 12 infrared absorption bands: ν₃(A₁), ν₆(E), ν₅(E), 2ν₃(A₁), 2ν₆(A₁), 2ν₆(E), ν₃ + ν₆(E), 2ν₅(A₁), 2ν₅(E), ν₃ + ν₅(E), ν₅ + ν₆(A₁ + A₂), and ν₅ + ν₆(E). More than 2500 "forbidden" transitions were used to determine the parameters C, D_K, and H_K. a₁ - a₂ (K = 3) splittings in the ground vibrational state were found and analyzed.

Язык оригинала	Английский
Страницы (с-по)	230-238
Число страниц	9
Журнал	Journal of Molecular Spectroscopy
Том	186
Номер выпуска	2
DOI	https://doi.org/10.1006/jmsp.1997.7433
Состояние	Опубликовано - 1 янв 1997

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

Доступ к документу

10.1006/jmsp.1997.7433

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Цитировать

A New Rotational Study of the Ground Vibrational State of CHD₃ . / Ulenikov, O. N.; Onopenko, G. A.; Tyabaeva, N. E.; Alanko, S.; Koivusaari, M.; Anttila, R.

В: Journal of Molecular Spectroscopy, Том 186, № 2, 01.01.1997, стр. 230-238.

Результат исследований: Материалы для журнала › Статья › рецензирование

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AU - Tyabaeva, N. E.

AU - Alanko, S.

AU - Koivusaari, M.

AU - Anttila, R.

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