The dependences of the shifts of the SKα-line on the magnitude of the effective charge on the sulfur atom, found by the electronegativity equalization method, agree well with those in which the charges on the sulfur atoms are calculated by ab initio and CNDO/S quantum chemical methods. The dependences of the shifts of the SKα-line (E=S, P, Cl, Si) on the magnitudes of the effective charge on the E atoms, found by equalization of the electronegativities, can be successfully used to determine the magnitudes of the charge on the E atoms on the same charge magnitude scale.
|Number of pages||2|
|Journal||Bulletin of the Academy of Sciences of the USSR Division of Chemical Science|
|Publication status||Published - Nov 1989|
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