X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes

G. N. Dolenko, O. Kh Poleshchuk, V. P. Elin, A. L. Litvin, I. V. Udachin, A. L. Ivanovskii

    Research output: Contribution to journalArticle

    3 Citations (Scopus)

    Abstract

    We have established that the total electron density on the chlorine atoms in SnCl4L2 complexes remains virtually unchanged compared with the original acceptor in strong complexes, decreases with weak complexes, and markedly increases in all the studied TiCl4L2 complexes. We show that the negative charge decreases on the chlorine atoms in the acceptor part of SnCl4L2 trans complexes, with square planar SnCl4, compared with the original tetrahedral configuration.

    Original languageEnglish
    Pages (from-to)2314-2317
    Number of pages4
    JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
    Volume38
    Issue number11
    DOIs
    Publication statusPublished - Nov 1989

    ASJC Scopus subject areas

    • Chemistry(all)

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