X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes

Abstract

We have established that the total electron density on the chlorine atoms in SnCl₄L₂ complexes remains virtually unchanged compared with the original acceptor in strong complexes, decreases with weak complexes, and markedly increases in all the studied TiCl₄L₂ complexes. We show that the negative charge decreases on the chlorine atoms in the acceptor part of SnCl₄L₂ trans complexes, with square planar SnCl₄, compared with the original tetrahedral configuration.

Original language	English
Pages (from-to)	2314-2317
Number of pages	4
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	38
Issue number	11
DOIs	https://doi.org/10.1007/BF01168077
Publication status	Published - Nov 1989

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10.1007/BF01168077

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Dolenko, G. N., Poleshchuk, O. K., Elin, V. P., Litvin, A. L., Udachin, I. V., & Ivanovskii, A. L. (1989). X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 38(11), 2314-2317. https://doi.org/10.1007/BF01168077

X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes. / Dolenko, G. N.; Poleshchuk, O. Kh; Elin, V. P.; Litvin, A. L.; Udachin, I. V.; Ivanovskii, A. L.

In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 38, No. 11, 11.1989, p. 2314-2317.

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Dolenko, GN, Poleshchuk, OK, Elin, VP, Litvin, AL, Udachin, IV & Ivanovskii, AL 1989, 'X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes', Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, vol. 38, no. 11, pp. 2314-2317. https://doi.org/10.1007/BF01168077

Dolenko, G. N. ; Poleshchuk, O. Kh ; Elin, V. P. ; Litvin, A. L. ; Udachin, I. V. ; Ivanovskii, A. L. / X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes. In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1989 ; Vol. 38, No. 11. pp. 2314-2317.

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abstract = "We have established that the total electron density on the chlorine atoms in SnCl4L2 complexes remains virtually unchanged compared with the original acceptor in strong complexes, decreases with weak complexes, and markedly increases in all the studied TiCl4L2 complexes. We show that the negative charge decreases on the chlorine atoms in the acceptor part of SnCl4L2 trans complexes, with square planar SnCl4, compared with the original tetrahedral configuration.",

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AU - Litvin, A. L.

AU - Udachin, I. V.

AU - Ivanovskii, A. L.

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X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes

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