We have established that the total electron density on the chlorine atoms in SnCl4L2 complexes remains virtually unchanged compared with the original acceptor in strong complexes, decreases with weak complexes, and markedly increases in all the studied TiCl4L2 complexes. We show that the negative charge decreases on the chlorine atoms in the acceptor part of SnCl4L2 trans complexes, with square planar SnCl4, compared with the original tetrahedral configuration.
|Number of pages||4|
|Journal||Bulletin of the Academy of Sciences of the USSR Division of Chemical Science|
|Publication status||Published - Nov 1989|
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