X-ray diffraction study of α-34S within temperature range 100–363 K

S. A. Gromilov, D. A. Piryazev, N. B. Egorov, D. V. Akimov

Research output: Contribution to journalArticle

Abstract

α-34S has been studied with X-ray crystallography within 100–363 K. Anisotropy of the evolution of the parameters of the orthorhombic unit cell has been examined. The absolute increase in the cell volume is 154 Å3, and the relative one is 4.8%. It has been demonstrated that in the studied range the intramolecular S–S bond lengths are shortened at average by 0.006 Å on heating. At the same time, intermolecular contacts S…S shorter than the sum of van der Waals radii demonstrate average elongation of 0.097 Å.

Original languageEnglish
Pages (from-to)1663-1666
Number of pages4
JournalJournal of Structural Chemistry
Volume57
Issue number8
DOIs
Publication statusPublished - 1 Dec 2016

Keywords

  • crystal chemistry
  • isotope
  • sulfur
  • X-ray crystallography

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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