Abstract
α-34S has been studied with X-ray crystallography within 100–363 K. Anisotropy of the evolution of the parameters of the orthorhombic unit cell has been examined. The absolute increase in the cell volume is 154 Å3, and the relative one is 4.8%. It has been demonstrated that in the studied range the intramolecular S–S bond lengths are shortened at average by 0.006 Å on heating. At the same time, intermolecular contacts S…S shorter than the sum of van der Waals radii demonstrate average elongation of 0.097 Å.
| Original language | English |
|---|---|
| Pages (from-to) | 1663-1666 |
| Number of pages | 4 |
| Journal | Journal of Structural Chemistry |
| Volume | 57 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 1 Dec 2016 |
Keywords
- crystal chemistry
- isotope
- sulfur
- X-ray crystallography
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
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Gromilov, S. A., Piryazev, D. A., Egorov, N. B., & Akimov, D. V. (2016). X-ray diffraction study of α-34S within temperature range 100–363 K. Journal of Structural Chemistry, 57(8), 1663-1666. https://doi.org/10.1134/S0022476616080230