Water-vapor absorption spectrum in the 0.59-μm region

A. B. Antipov, A. D. Bykov, V. A. Kapitanov, V. P. Lopasov, Yu S. Makushkin, V. I. Tolmachev, O. N. Ulenikov, V. E. Zuev

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Abstract

The paper gives the results of investigation of the water-vapor absorption spectrum in the range of 586.9-596.6 nm. In the given range, 282 water-vapor absorption lines were recorded and were identified as belonging to the bands 4ν1 + ν3, 3ν1 + 2ν2 + ν3, 3ν1 + 2ν3. Theoretical justification of the technique for interpreting the observed spectrum was made. The values of more vibration-rotation levels of energy were determined: for state (401) up to J = 10, for state (321) up to J = 10, and for state (302) up to J = 8. The rotational and centrifugal constants of the reduced Watson's Hamiltonian for the vibrational states (401), (321), (302), and (222) and constants of Fermi resonance (401)-(321), (302)-(222), and Coriolis resonance between the states (401), (321), and (302), (222) were determined.

Original languageEnglish
Pages (from-to)449-459
Number of pages11
JournalJournal of Molecular Spectroscopy
Volume89
Issue number2
DOIs
Publication statusPublished - 1981
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

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    Antipov, A. B., Bykov, A. D., Kapitanov, V. A., Lopasov, V. P., Makushkin, Y. S., Tolmachev, V. I., Ulenikov, O. N., & Zuev, V. E. (1981). Water-vapor absorption spectrum in the 0.59-μm region. Journal of Molecular Spectroscopy, 89(2), 449-459. https://doi.org/10.1016/0022-2852(81)90038-2