Voltammetry behavior of iodine and selenium on new organo-modified electrodes: Development of a procedure for the determination of iodine and selenium

Abstract

The voltammetry behavior of iodine and selenium has been studied on new organo-modified electrodes. The conditions have been proposed for the measurement of the analytical signals of iodide and selenium ions on a silver electrode modified by aryl diazonium tosylates containing an amino group in the presence of a 0.1 M solution of N₂H₄ · H ₂SO₄ (pH 2-3) without oxygen removal. A new approach and a procedure have been developed for the simultaneous determination of iodine and selenium in tap, drinking, and mineral waters using the organo-modified electrode. The analytical range is from 0.003 to 1.5 mg/L for iodide ions and from 0.003 to 2.0 mg/L for selenite ions.

Original language	English
Pages (from-to)	896-899
Number of pages	4
Journal	Journal of Analytical Chemistry
Volume	68
Issue number	10
DOIs	https://doi.org/10.1134/S1061934813100043
Publication status	Published - Oct 2013

Keywords

aryl diazonium salts
drinking water
iodine
mineral water
organo-modified electrode
selenium
tap water
voltammetry

ASJC Scopus subject areas

Analytical Chemistry

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10.1134/S1061934813100043

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@article{a35b8832cb3b4d1c80bb911b43602984,

title = "Voltammetry behavior of iodine and selenium on new organo-modified electrodes: Development of a procedure for the determination of iodine and selenium",

abstract = "The voltammetry behavior of iodine and selenium has been studied on new organo-modified electrodes. The conditions have been proposed for the measurement of the analytical signals of iodide and selenium ions on a silver electrode modified by aryl diazonium tosylates containing an amino group in the presence of a 0.1 M solution of N2H4 · H 2SO4 (pH 2-3) without oxygen removal. A new approach and a procedure have been developed for the simultaneous determination of iodine and selenium in tap, drinking, and mineral waters using the organo-modified electrode. The analytical range is from 0.003 to 1.5 mg/L for iodide ions and from 0.003 to 2.0 mg/L for selenite ions.",

keywords = "aryl diazonium salts, drinking water, iodine, mineral water, organo-modified electrode, selenium, tap water, voltammetry",

author = "Deryabina, {V. I.} and Slepchenko, {G. B.} and N'Ung, {Fam Kam} and Lin', {Ho Shi}",

year = "2013",

month = oct,

doi = "10.1134/S1061934813100043",

language = "English",

volume = "68",

pages = "896--899",

journal = "Journal of Analytical Chemistry",

issn = "1061-9348",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "10",

}

TY - JOUR

T1 - Voltammetry behavior of iodine and selenium on new organo-modified electrodes

T2 - Development of a procedure for the determination of iodine and selenium

AU - Deryabina, V. I.

AU - Slepchenko, G. B.

AU - N'Ung, Fam Kam

AU - Lin', Ho Shi

PY - 2013/10

Y1 - 2013/10

N2 - The voltammetry behavior of iodine and selenium has been studied on new organo-modified electrodes. The conditions have been proposed for the measurement of the analytical signals of iodide and selenium ions on a silver electrode modified by aryl diazonium tosylates containing an amino group in the presence of a 0.1 M solution of N2H4 · H 2SO4 (pH 2-3) without oxygen removal. A new approach and a procedure have been developed for the simultaneous determination of iodine and selenium in tap, drinking, and mineral waters using the organo-modified electrode. The analytical range is from 0.003 to 1.5 mg/L for iodide ions and from 0.003 to 2.0 mg/L for selenite ions.

AB - The voltammetry behavior of iodine and selenium has been studied on new organo-modified electrodes. The conditions have been proposed for the measurement of the analytical signals of iodide and selenium ions on a silver electrode modified by aryl diazonium tosylates containing an amino group in the presence of a 0.1 M solution of N2H4 · H 2SO4 (pH 2-3) without oxygen removal. A new approach and a procedure have been developed for the simultaneous determination of iodine and selenium in tap, drinking, and mineral waters using the organo-modified electrode. The analytical range is from 0.003 to 1.5 mg/L for iodide ions and from 0.003 to 2.0 mg/L for selenite ions.

KW - aryl diazonium salts

KW - drinking water

KW - iodine

KW - mineral water

KW - organo-modified electrode

KW - selenium

KW - tap water

KW - voltammetry

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JO - Journal of Analytical Chemistry

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SN - 1061-9348

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