Voltammetric Determination of Cymoxanil and Famoxadone at Different Types of Carbon Electrodes

Abstract

Differential pulse voltammetry (DPV) at a carbon fibre rod electrode (CFRE) and a capillary carbon paste electrode (CPE) have been used for the determination of pesticides cymoxanil and famoxadone, respectively. In the cathodic potential range, optimum conditions were found for the determination of cymoxanil by DPV at CFRE at pH4 with limit of quantification (L_Q) of 5.9×10^-7molL^-1. In the anodic area, determination of famoxadone by DPV at CPE was performed at optimum pH2 with L_Q=1.4×10^-7molL^-1. Practical applicability of the newly developed methods was verified on spiked samples of river water and soil.

Original language	English
Pages (from-to)	1029-1034
Number of pages	6
Journal	Electroanalysis
Volume	28
Issue number	5
DOIs	https://doi.org/10.1002/elan.201500633
Publication status	Published - 1 May 2016
Externally published	Yes

Keywords

Carbon fiber rod electrode
Carbon paste electrode
Differential pulse voltammetry
Glassy carbon electrode
Pesticide

ASJC Scopus subject areas

Analytical Chemistry
Electrochemistry

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10.1002/elan.201500633

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@article{e150008312834b6a8af754593623387b,

title = "Voltammetric Determination of Cymoxanil and Famoxadone at Different Types of Carbon Electrodes",

abstract = "Differential pulse voltammetry (DPV) at a carbon fibre rod electrode (CFRE) and a capillary carbon paste electrode (CPE) have been used for the determination of pesticides cymoxanil and famoxadone, respectively. In the cathodic potential range, optimum conditions were found for the determination of cymoxanil by DPV at CFRE at pH4 with limit of quantification (LQ) of 5.9×10-7molL-1. In the anodic area, determination of famoxadone by DPV at CPE was performed at optimum pH2 with LQ=1.4×10-7molL-1. Practical applicability of the newly developed methods was verified on spiked samples of river water and soil.",

keywords = "Carbon fiber rod electrode, Carbon paste electrode, Differential pulse voltammetry, Glassy carbon electrode, Pesticide",

author = "Dmytro Bavol and Jiri Zima and Jiri Barek and Hana Dejmkova",

year = "2016",

month = may,

day = "1",

doi = "10.1002/elan.201500633",

language = "English",

volume = "28",

pages = "1029--1034",

journal = "Macromolecular Chemistry and Physics",

issn = "1040-0397",

publisher = "Wiley-VCH Verlag",

number = "5",

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TY - JOUR

T1 - Voltammetric Determination of Cymoxanil and Famoxadone at Different Types of Carbon Electrodes

AU - Bavol, Dmytro

AU - Zima, Jiri

AU - Barek, Jiri

AU - Dejmkova, Hana

PY - 2016/5/1

Y1 - 2016/5/1

N2 - Differential pulse voltammetry (DPV) at a carbon fibre rod electrode (CFRE) and a capillary carbon paste electrode (CPE) have been used for the determination of pesticides cymoxanil and famoxadone, respectively. In the cathodic potential range, optimum conditions were found for the determination of cymoxanil by DPV at CFRE at pH4 with limit of quantification (LQ) of 5.9×10-7molL-1. In the anodic area, determination of famoxadone by DPV at CPE was performed at optimum pH2 with LQ=1.4×10-7molL-1. Practical applicability of the newly developed methods was verified on spiked samples of river water and soil.

AB - Differential pulse voltammetry (DPV) at a carbon fibre rod electrode (CFRE) and a capillary carbon paste electrode (CPE) have been used for the determination of pesticides cymoxanil and famoxadone, respectively. In the cathodic potential range, optimum conditions were found for the determination of cymoxanil by DPV at CFRE at pH4 with limit of quantification (LQ) of 5.9×10-7molL-1. In the anodic area, determination of famoxadone by DPV at CPE was performed at optimum pH2 with LQ=1.4×10-7molL-1. Practical applicability of the newly developed methods was verified on spiked samples of river water and soil.

KW - Carbon fiber rod electrode

KW - Carbon paste electrode

KW - Differential pulse voltammetry

KW - Glassy carbon electrode

KW - Pesticide

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