Voltammetric determination of aliphatic phthalate esters at a hanging mercury drop minielectrode and a meniscus modified silver solid amalgam electrode

Abstract

A new simple, fast and sensitive differential pulse voltammetric method was developed for the determination of different aliphatic phthalates. Dibutyl phthalate, diethyl phthalate, didecyl phthalate, and diallyl phthalate can be determined in 0.1 M tetramethylammonium bromide in methanol using a hanging mercury drop minielectrode and a meniscus modified silver solid amalgam electrode. Optimum conditions were found including concentration and composition of supporting electrolyte and solvent, scan rate, pulse amplitude, pulse width, etc. Linear calibration curves were obtained for 10^-5 and 10^-6 M and for hanging mercury drop minielectrode also for 10^-7 M.

Original language	English
Pages (from-to)	1957-1962
Number of pages	6
Journal	Electroanalysis
Volume	22
Issue number	17-18
DOIs	https://doi.org/10.1002/elan.201000040
Publication status	Published - 20 Sep 2010
Externally published	Yes

Keywords

Diallyl phthalate
Dibutyl phthalate
Didecyl phthalate
Diethyl phthalate
Differential pulse voltammetry
Hanging mercury drop minielectrode
Meniscus modified silver solid amalgam electrode
Voltammetry

ASJC Scopus subject areas

Analytical Chemistry
Electrochemistry

Access to Document

10.1002/elan.201000040

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Voltammetric determination of aliphatic phthalate esters at a hanging mercury drop minielectrode and a meniscus modified silver solid amalgam electrode. / Qureshi, Munawar Saeed; Fischer, Jan; Barek, Jiří; Sirajuddin; Bhanger, Muhammad Iqbal.

In: Electroanalysis, Vol. 22, No. 17-18, 20.09.2010, p. 1957-1962.

Research output: Contribution to journal › Article › peer-review

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abstract = "A new simple, fast and sensitive differential pulse voltammetric method was developed for the determination of different aliphatic phthalates. Dibutyl phthalate, diethyl phthalate, didecyl phthalate, and diallyl phthalate can be determined in 0.1 M tetramethylammonium bromide in methanol using a hanging mercury drop minielectrode and a meniscus modified silver solid amalgam electrode. Optimum conditions were found including concentration and composition of supporting electrolyte and solvent, scan rate, pulse amplitude, pulse width, etc. Linear calibration curves were obtained for 10-5 and 10-6 M and for hanging mercury drop minielectrode also for 10-7 M.",

keywords = "Diallyl phthalate, Dibutyl phthalate, Didecyl phthalate, Diethyl phthalate, Differential pulse voltammetry, Hanging mercury drop minielectrode, Meniscus modified silver solid amalgam electrode, Voltammetry",

author = "Qureshi, {Munawar Saeed} and Jan Fischer and Ji{\v r}{\'i} Barek and Sirajuddin and Bhanger, {Muhammad Iqbal}",

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AU - Qureshi, Munawar Saeed

AU - Fischer, Jan

AU - Barek, Jiří

AU - Sirajuddin,

AU - Bhanger, Muhammad Iqbal

PY - 2010/9/20

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N2 - A new simple, fast and sensitive differential pulse voltammetric method was developed for the determination of different aliphatic phthalates. Dibutyl phthalate, diethyl phthalate, didecyl phthalate, and diallyl phthalate can be determined in 0.1 M tetramethylammonium bromide in methanol using a hanging mercury drop minielectrode and a meniscus modified silver solid amalgam electrode. Optimum conditions were found including concentration and composition of supporting electrolyte and solvent, scan rate, pulse amplitude, pulse width, etc. Linear calibration curves were obtained for 10-5 and 10-6 M and for hanging mercury drop minielectrode also for 10-7 M.

AB - A new simple, fast and sensitive differential pulse voltammetric method was developed for the determination of different aliphatic phthalates. Dibutyl phthalate, diethyl phthalate, didecyl phthalate, and diallyl phthalate can be determined in 0.1 M tetramethylammonium bromide in methanol using a hanging mercury drop minielectrode and a meniscus modified silver solid amalgam electrode. Optimum conditions were found including concentration and composition of supporting electrolyte and solvent, scan rate, pulse amplitude, pulse width, etc. Linear calibration curves were obtained for 10-5 and 10-6 M and for hanging mercury drop minielectrode also for 10-7 M.

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KW - Didecyl phthalate

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KW - Differential pulse voltammetry

KW - Hanging mercury drop minielectrode

KW - Meniscus modified silver solid amalgam electrode

KW - Voltammetry

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