Abstract
A rapid simple fabrication method for the bismuth bulk working electrode is reported using a Pasteur pipette tip filled with molten bismuth to form a disk. The applicability of the newly developed electrode was verified by differential pulse voltammetric determination of 5-nitroindazole, which is a reagent for organic synthesis. The 5-nitroindazole shows high toxicity against parasites from the Trypanosomatidae family and it is a proven mutagen for bacterial cultures. A Britton-Robinson buffer of pH 8.0 was chosen as the optimal medium for this determination. The calibration curve was measured from 2 to 100 micromoles per liter (r = −0.9989) with limits of detection and quantification of 0.20 and 0.67 micromole per liter, respectively. The developed method was successfully applied for the analysis of drinking and river water.
| Original language | English |
|---|---|
| Pages (from-to) | 49-55 |
| Number of pages | 7 |
| Journal | Analytical Letters |
| Volume | 49 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2 Jan 2016 |
| Externally published | Yes |
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Keywords
- 5-Nitroindazole
- bismuth bulk electrode
- differential pulse voltammetry
ASJC Scopus subject areas
- Analytical Chemistry
- Biochemistry
- Clinical Biochemistry
- Biochemistry, medical
- Electrochemistry
- Spectroscopy
Cite this
Voltammetric Determination of 5-nitroindazole using a Bismuth Bulk Electrode. / Prchal, Vit; Ottenschlagerova, Anita; Vyskocil, Vlastimil; Barek, Jiri.
In: Analytical Letters, Vol. 49, No. 1, 02.01.2016, p. 49-55.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Voltammetric Determination of 5-nitroindazole using a Bismuth Bulk Electrode
AU - Prchal, Vit
AU - Ottenschlagerova, Anita
AU - Vyskocil, Vlastimil
AU - Barek, Jiri
PY - 2016/1/2
Y1 - 2016/1/2
N2 - A rapid simple fabrication method for the bismuth bulk working electrode is reported using a Pasteur pipette tip filled with molten bismuth to form a disk. The applicability of the newly developed electrode was verified by differential pulse voltammetric determination of 5-nitroindazole, which is a reagent for organic synthesis. The 5-nitroindazole shows high toxicity against parasites from the Trypanosomatidae family and it is a proven mutagen for bacterial cultures. A Britton-Robinson buffer of pH 8.0 was chosen as the optimal medium for this determination. The calibration curve was measured from 2 to 100 micromoles per liter (r = −0.9989) with limits of detection and quantification of 0.20 and 0.67 micromole per liter, respectively. The developed method was successfully applied for the analysis of drinking and river water.
AB - A rapid simple fabrication method for the bismuth bulk working electrode is reported using a Pasteur pipette tip filled with molten bismuth to form a disk. The applicability of the newly developed electrode was verified by differential pulse voltammetric determination of 5-nitroindazole, which is a reagent for organic synthesis. The 5-nitroindazole shows high toxicity against parasites from the Trypanosomatidae family and it is a proven mutagen for bacterial cultures. A Britton-Robinson buffer of pH 8.0 was chosen as the optimal medium for this determination. The calibration curve was measured from 2 to 100 micromoles per liter (r = −0.9989) with limits of detection and quantification of 0.20 and 0.67 micromole per liter, respectively. The developed method was successfully applied for the analysis of drinking and river water.
KW - 5-Nitroindazole
KW - bismuth bulk electrode
KW - differential pulse voltammetry
UR - http://www.scopus.com/inward/record.url?scp=84944931109&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84944931109&partnerID=8YFLogxK
U2 - 10.1080/00032719.2014.996810
DO - 10.1080/00032719.2014.996810
M3 - Article
VL - 49
SP - 49
EP - 55
JO - Analytical Letters
JF - Analytical Letters
SN - 0003-2719
IS - 1
ER -