Abstract
Direct current (DC) voltammetry and differential pulse (DP) voltammetry using a carbon paste electrode (CPE) have been used for the determination of trace amounts of ecotoxic 1,2-diaminoanthraquinone (DAAQ). The limit of determination (LD) of DAAQ for DC voltammetry was 2 × 10 -6 mol l-1, and for DP voltammetry 2 × 10 -7 mol l-1 under the optimized conditions in a mixed Britton-Robinson buffer pH 12 and methanol (1:9) medium. Adsorptive accummulation of the analyte on the surface of CPE decreased the limit of determination to 2 × 10-8 mol l-1 for DP voltammetry. Practical applicability of these newly developed methods was verified on model samples of river water.
| Original language | English |
|---|---|
| Pages (from-to) | 1033-1041 |
| Number of pages | 9 |
| Journal | Collection of Czechoslovak Chemical Communications |
| Volume | 76 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 22 Aug 2011 |
| Externally published | Yes |
Fingerprint
Keywords
- 1,2-diaminoanthraquinone
- Adsorptive stripping voltammetry
- Analytical methods
- Carbon paste electrode
- Differential pulse voltammetry
- Direct current voltammetry
- Electrochemistry
- Voltammetry
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Voltammetric determination of 1,2-diaminoanthraquinone using carbon paste electrode. / Zima, Jiří; Tinková, Veronika; Wang, Joseph; Barek, Jiří.
In: Collection of Czechoslovak Chemical Communications, Vol. 76, No. 8, 22.08.2011, p. 1033-1041.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Voltammetric determination of 1,2-diaminoanthraquinone using carbon paste electrode
AU - Zima, Jiří
AU - Tinková, Veronika
AU - Wang, Joseph
AU - Barek, Jiří
PY - 2011/8/22
Y1 - 2011/8/22
N2 - Direct current (DC) voltammetry and differential pulse (DP) voltammetry using a carbon paste electrode (CPE) have been used for the determination of trace amounts of ecotoxic 1,2-diaminoanthraquinone (DAAQ). The limit of determination (LD) of DAAQ for DC voltammetry was 2 × 10 -6 mol l-1, and for DP voltammetry 2 × 10 -7 mol l-1 under the optimized conditions in a mixed Britton-Robinson buffer pH 12 and methanol (1:9) medium. Adsorptive accummulation of the analyte on the surface of CPE decreased the limit of determination to 2 × 10-8 mol l-1 for DP voltammetry. Practical applicability of these newly developed methods was verified on model samples of river water.
AB - Direct current (DC) voltammetry and differential pulse (DP) voltammetry using a carbon paste electrode (CPE) have been used for the determination of trace amounts of ecotoxic 1,2-diaminoanthraquinone (DAAQ). The limit of determination (LD) of DAAQ for DC voltammetry was 2 × 10 -6 mol l-1, and for DP voltammetry 2 × 10 -7 mol l-1 under the optimized conditions in a mixed Britton-Robinson buffer pH 12 and methanol (1:9) medium. Adsorptive accummulation of the analyte on the surface of CPE decreased the limit of determination to 2 × 10-8 mol l-1 for DP voltammetry. Practical applicability of these newly developed methods was verified on model samples of river water.
KW - 1,2-diaminoanthraquinone
KW - Adsorptive stripping voltammetry
KW - Analytical methods
KW - Carbon paste electrode
KW - Differential pulse voltammetry
KW - Direct current voltammetry
KW - Electrochemistry
KW - Voltammetry
UR - http://www.scopus.com/inward/record.url?scp=80051779510&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=80051779510&partnerID=8YFLogxK
U2 - 10.1135/cccc2011068
DO - 10.1135/cccc2011068
M3 - Article
AN - SCOPUS:80051779510
VL - 76
SP - 1033
EP - 1041
JO - Collection of Czechoslovak Chemical Communications
JF - Collection of Czechoslovak Chemical Communications
SN - 0010-0765
IS - 8
ER -