Abstract
Optimum conditions for the determination of carcinogenic 1-nitropyrene (NP) and 1-aminopyrene (AP) by differential pulse voltammetry with a boron-doped diamond film electrode were found - aqueous-methanolic (3:7) Britton-Robinson buffer (pH 3), scan rate 20 mV s-1, pulse duration 100 ms, pulse amplitude -50 mV (NP) and 50 mV (AP). The regeneration in NP determination was carried out before analysis by switching fifty-times between the potentials 800 mV and -500 mV every 0.3 s. In determination of AP, no regeneration was needed. The limits of quantification were 8·10-7 and 2·10-7 mol dm-3 for NP and AP, respectively.
| Original language | Czech |
|---|---|
| Pages (from-to) | 186-190 |
| Number of pages | 5 |
| Journal | Chemicke Listy |
| Volume | 104 |
| Issue number | 3 |
| Publication status | Published - 16 Mar 2010 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Voltametrické stanovení 1-nitropyrenu a 1-aminopyrenu na borem dopované diamantové filmové elektrodě. / Yosypchuk, Oksana; Pecková, Karolina; Barek, Jiří.
In: Chemicke Listy, Vol. 104, No. 3, 16.03.2010, p. 186-190.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Voltametrické stanovení 1-nitropyrenu a 1-aminopyrenu na borem dopované diamantové filmové elektrodě
AU - Yosypchuk, Oksana
AU - Pecková, Karolina
AU - Barek, Jiří
PY - 2010/3/16
Y1 - 2010/3/16
N2 - Optimum conditions for the determination of carcinogenic 1-nitropyrene (NP) and 1-aminopyrene (AP) by differential pulse voltammetry with a boron-doped diamond film electrode were found - aqueous-methanolic (3:7) Britton-Robinson buffer (pH 3), scan rate 20 mV s-1, pulse duration 100 ms, pulse amplitude -50 mV (NP) and 50 mV (AP). The regeneration in NP determination was carried out before analysis by switching fifty-times between the potentials 800 mV and -500 mV every 0.3 s. In determination of AP, no regeneration was needed. The limits of quantification were 8·10-7 and 2·10-7 mol dm-3 for NP and AP, respectively.
AB - Optimum conditions for the determination of carcinogenic 1-nitropyrene (NP) and 1-aminopyrene (AP) by differential pulse voltammetry with a boron-doped diamond film electrode were found - aqueous-methanolic (3:7) Britton-Robinson buffer (pH 3), scan rate 20 mV s-1, pulse duration 100 ms, pulse amplitude -50 mV (NP) and 50 mV (AP). The regeneration in NP determination was carried out before analysis by switching fifty-times between the potentials 800 mV and -500 mV every 0.3 s. In determination of AP, no regeneration was needed. The limits of quantification were 8·10-7 and 2·10-7 mol dm-3 for NP and AP, respectively.
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M3 - Статья
VL - 104
SP - 186
EP - 190
JO - Chemicke Listy
JF - Chemicke Listy
SN - 0009-2770
IS - 3
ER -