Voltammetric and Amperometric Determination of Mixtures of Aminobiphenyls and Aminonaphthalenes Using Boron Doped Diamond Electrode

Jaroslava Zavázalová, Hana Dejmková, Jiří Barek, Karolina Pecková

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

An anodically pretreated boron-doped diamond (BDD) electrode was used for the voltammetric and amperometric determination of the genotoxic pollutants 2-aminobiphenyl, 4-aminobiphenyl, 1-aminonaphthalene, and 2-aminonaphthalene. Their simultaneous voltammetric determination is only possible when the difference of the peak potentials of the particular analytes is higher than ca. 140mV. Their complete separation using high performance liquid chromatography (HPLC) with amperometric detection at a BDD film electrode in wall-jet arrangement results in limits of detection in the 10-8molL-1 concentration range and can be lowered to nanomolar concentrations, as demonstrated by their determination in azo dye sunset yellow using solid-phase extraction at Lichrolut EN cartridges.

Original languageEnglish
Pages (from-to)253-262
Number of pages10
JournalElectroanalysis
Volume25
Issue number1
DOIs
Publication statusPublished - 1 Jan 2013
Externally publishedYes

Fingerprint

Diamond
Boron
Diamonds
Azo Compounds
1-Naphthylamine
2-Naphthylamine
Electrodes
Azo dyes
Diamond films
High performance liquid chromatography
FD & C Yellow No. 6
4-biphenylamine
2-aminodiphenyl

Keywords

  • Amino aromatics
  • Amperometry
  • Boron-doped diamond film electrode
  • Dyes/Pigments
  • Voltammetry

ASJC Scopus subject areas

  • Analytical Chemistry
  • Electrochemistry

Cite this

Voltammetric and Amperometric Determination of Mixtures of Aminobiphenyls and Aminonaphthalenes Using Boron Doped Diamond Electrode. / Zavázalová, Jaroslava; Dejmková, Hana; Barek, Jiří; Pecková, Karolina.

In: Electroanalysis, Vol. 25, No. 1, 01.01.2013, p. 253-262.

Research output: Contribution to journalArticle

Zavázalová, Jaroslava ; Dejmková, Hana ; Barek, Jiří ; Pecková, Karolina. / Voltammetric and Amperometric Determination of Mixtures of Aminobiphenyls and Aminonaphthalenes Using Boron Doped Diamond Electrode. In: Electroanalysis. 2013 ; Vol. 25, No. 1. pp. 253-262.
@article{f847770b7eaa4517962cd36831c754c5,
title = "Voltammetric and Amperometric Determination of Mixtures of Aminobiphenyls and Aminonaphthalenes Using Boron Doped Diamond Electrode",
abstract = "An anodically pretreated boron-doped diamond (BDD) electrode was used for the voltammetric and amperometric determination of the genotoxic pollutants 2-aminobiphenyl, 4-aminobiphenyl, 1-aminonaphthalene, and 2-aminonaphthalene. Their simultaneous voltammetric determination is only possible when the difference of the peak potentials of the particular analytes is higher than ca. 140mV. Their complete separation using high performance liquid chromatography (HPLC) with amperometric detection at a BDD film electrode in wall-jet arrangement results in limits of detection in the 10-8molL-1 concentration range and can be lowered to nanomolar concentrations, as demonstrated by their determination in azo dye sunset yellow using solid-phase extraction at Lichrolut EN cartridges.",
keywords = "Amino aromatics, Amperometry, Boron-doped diamond film electrode, Dyes/Pigments, Voltammetry",
author = "Jaroslava Zav{\'a}zalov{\'a} and Hana Dejmkov{\'a} and Jiř{\'i} Barek and Karolina Peckov{\'a}",
year = "2013",
month = "1",
day = "1",
doi = "10.1002/elan.201200424",
language = "English",
volume = "25",
pages = "253--262",
journal = "Macromolecular Chemistry and Physics",
issn = "1040-0397",
publisher = "Wiley-VCH Verlag",
number = "1",

}

TY - JOUR

T1 - Voltammetric and Amperometric Determination of Mixtures of Aminobiphenyls and Aminonaphthalenes Using Boron Doped Diamond Electrode

AU - Zavázalová, Jaroslava

AU - Dejmková, Hana

AU - Barek, Jiří

AU - Pecková, Karolina

PY - 2013/1/1

Y1 - 2013/1/1

N2 - An anodically pretreated boron-doped diamond (BDD) electrode was used for the voltammetric and amperometric determination of the genotoxic pollutants 2-aminobiphenyl, 4-aminobiphenyl, 1-aminonaphthalene, and 2-aminonaphthalene. Their simultaneous voltammetric determination is only possible when the difference of the peak potentials of the particular analytes is higher than ca. 140mV. Their complete separation using high performance liquid chromatography (HPLC) with amperometric detection at a BDD film electrode in wall-jet arrangement results in limits of detection in the 10-8molL-1 concentration range and can be lowered to nanomolar concentrations, as demonstrated by their determination in azo dye sunset yellow using solid-phase extraction at Lichrolut EN cartridges.

AB - An anodically pretreated boron-doped diamond (BDD) electrode was used for the voltammetric and amperometric determination of the genotoxic pollutants 2-aminobiphenyl, 4-aminobiphenyl, 1-aminonaphthalene, and 2-aminonaphthalene. Their simultaneous voltammetric determination is only possible when the difference of the peak potentials of the particular analytes is higher than ca. 140mV. Their complete separation using high performance liquid chromatography (HPLC) with amperometric detection at a BDD film electrode in wall-jet arrangement results in limits of detection in the 10-8molL-1 concentration range and can be lowered to nanomolar concentrations, as demonstrated by their determination in azo dye sunset yellow using solid-phase extraction at Lichrolut EN cartridges.

KW - Amino aromatics

KW - Amperometry

KW - Boron-doped diamond film electrode

KW - Dyes/Pigments

KW - Voltammetry

UR - http://www.scopus.com/inward/record.url?scp=84872572195&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84872572195&partnerID=8YFLogxK

U2 - 10.1002/elan.201200424

DO - 10.1002/elan.201200424

M3 - Article

AN - SCOPUS:84872572195

VL - 25

SP - 253

EP - 262

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

SN - 1040-0397

IS - 1

ER -