### Abstract

The expression for the second - order transformed polarizability operator for non-linear X
_{2}Y - type molecules is derived using the method of contact transformation. This operator is used for the calculation of ro-vibrational Raman cross sections of the H
_{2}O molecule. It is shown that the ro-vibrational correction terms change the integral intensity of pure rotational lines significantly and the v
_{2} band slightly. The vibrational dependence of the mean polarizability of H
_{2}O is analyzed in the calculation of integral intensity of one and two quantum bands.

Original language | English |
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Title of host publication | Proceedings of SPIE - The International Society for Optical Engineering |

Editors | L.N. Sinitsa, S.N. Mikhailenko |

Pages | 148-155 |

Number of pages | 8 |

Volume | 5311 |

Publication status | Published - 2004 |

Event | 14th Symposium on High-Resolution Molecular Spectroscopy - Krasnoyarsk, Russian Federation Duration: 6 Jul 2003 → 11 Jul 2003 |

### Other

Other | 14th Symposium on High-Resolution Molecular Spectroscopy |
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Country | Russian Federation |

City | Krasnoyarsk |

Period | 6.7.03 → 11.7.03 |

### Fingerprint

### Keywords

- Raman cross sections of H O
- Transformed polarizability operator

### ASJC Scopus subject areas

- Electrical and Electronic Engineering
- Condensed Matter Physics

### Cite this

_{2}Y - type molecules and the ro-vibrational Raman cross sections calculation of water molecule. In L. N. Sinitsa, & S. N. Mikhailenko (Eds.),

*Proceedings of SPIE - The International Society for Optical Engineering*(Vol. 5311, pp. 148-155)

**Vibration-rotation polarizability operator for non-linear X
_{2}Y - type molecules and the ro-vibrational Raman cross sections calculation of water molecule.** / Starikov, V. I.; Protasevich, A. E.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

_{2}Y - type molecules and the ro-vibrational Raman cross sections calculation of water molecule. in LN Sinitsa & SN Mikhailenko (eds),

*Proceedings of SPIE - The International Society for Optical Engineering.*vol. 5311, pp. 148-155, 14th Symposium on High-Resolution Molecular Spectroscopy, Krasnoyarsk, Russian Federation, 6.7.03.

_{2}Y - type molecules and the ro-vibrational Raman cross sections calculation of water molecule. In Sinitsa LN, Mikhailenko SN, editors, Proceedings of SPIE - The International Society for Optical Engineering. Vol. 5311. 2004. p. 148-155

}

TY - GEN

T1 - Vibration-rotation polarizability operator for non-linear X 2Y - type molecules and the ro-vibrational Raman cross sections calculation of water molecule

AU - Starikov, V. I.

AU - Protasevich, A. E.

PY - 2004

Y1 - 2004

N2 - The expression for the second - order transformed polarizability operator for non-linear X 2Y - type molecules is derived using the method of contact transformation. This operator is used for the calculation of ro-vibrational Raman cross sections of the H 2O molecule. It is shown that the ro-vibrational correction terms change the integral intensity of pure rotational lines significantly and the v 2 band slightly. The vibrational dependence of the mean polarizability of H 2O is analyzed in the calculation of integral intensity of one and two quantum bands.

AB - The expression for the second - order transformed polarizability operator for non-linear X 2Y - type molecules is derived using the method of contact transformation. This operator is used for the calculation of ro-vibrational Raman cross sections of the H 2O molecule. It is shown that the ro-vibrational correction terms change the integral intensity of pure rotational lines significantly and the v 2 band slightly. The vibrational dependence of the mean polarizability of H 2O is analyzed in the calculation of integral intensity of one and two quantum bands.

KW - Raman cross sections of H O

KW - Transformed polarizability operator

UR - http://www.scopus.com/inward/record.url?scp=1842664379&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=1842664379&partnerID=8YFLogxK

M3 - Conference contribution

VL - 5311

SP - 148

EP - 155

BT - Proceedings of SPIE - The International Society for Optical Engineering

A2 - Sinitsa, L.N.

A2 - Mikhailenko, S.N.

ER -