Abstract
The systematic error in measuring the analytical signal of Pt obtained at a mercury thin-film electrode with staircase potential sweep has been studied. The description of the residual current by splines of degree 2.5 reduces the average systematic error by the factor of 4.3 as compared to the linear description. It is shown that splines of degree 2.5 are more stable as compared to the cubic splines, which suggests that the random error arising from the subtraction of the residual current is reduced when the spline degree decreases from 3 to 2.5.
| Original language | English |
|---|---|
| Pages (from-to) | 51-55 |
| Number of pages | 5 |
| Journal | Journal of Analytical Chemistry |
| Volume | 56 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2001 |
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ASJC Scopus subject areas
- Analytical Chemistry
Cite this
Use of a Spline Function of a Fractional Degree for the Description of the Base Line in the Determination of Platinum by Stripping Voltammetry. / Romanenko, S. V.; Romanenko, E. S.; Kolpakova, N. A.
In: Journal of Analytical Chemistry, Vol. 56, No. 1, 2001, p. 51-55.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Use of a Spline Function of a Fractional Degree for the Description of the Base Line in the Determination of Platinum by Stripping Voltammetry
AU - Romanenko, S. V.
AU - Romanenko, E. S.
AU - Kolpakova, N. A.
PY - 2001
Y1 - 2001
N2 - The systematic error in measuring the analytical signal of Pt obtained at a mercury thin-film electrode with staircase potential sweep has been studied. The description of the residual current by splines of degree 2.5 reduces the average systematic error by the factor of 4.3 as compared to the linear description. It is shown that splines of degree 2.5 are more stable as compared to the cubic splines, which suggests that the random error arising from the subtraction of the residual current is reduced when the spline degree decreases from 3 to 2.5.
AB - The systematic error in measuring the analytical signal of Pt obtained at a mercury thin-film electrode with staircase potential sweep has been studied. The description of the residual current by splines of degree 2.5 reduces the average systematic error by the factor of 4.3 as compared to the linear description. It is shown that splines of degree 2.5 are more stable as compared to the cubic splines, which suggests that the random error arising from the subtraction of the residual current is reduced when the spline degree decreases from 3 to 2.5.
UR - http://www.scopus.com/inward/record.url?scp=0043284201&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0043284201&partnerID=8YFLogxK
U2 - 10.1023/A:1026719512595
DO - 10.1023/A:1026719512595
M3 - Article
VL - 56
SP - 51
EP - 55
JO - Journal of Analytical Chemistry
JF - Journal of Analytical Chemistry
SN - 1061-9348
IS - 1
ER -