Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP)

A method for preparation of functional surfaces

Olga Guselnikova, Sylvain R.A. Marque, Evgeny V. Tretyakov, David Mares, Vitezslav Jerabek, Gérard Audran, Jean Patrick Joly, Marina Trusova, Vaclav Svorcik, Oleksiy Lyutakov, Pavel Postnikov

Research output: Contribution to journalArticle

Abstract

A plasmon as a stimulus opens up new opportunities for selective and regulated "from-surface" polymerization and functionalization of surfaces. Here, the first example of plasmon-assisted nitroxide-mediated polymerization (NMP) of stimuli-responsive block copolymers poly(N-isopropylacrylamide)-co-4-vinylboronic acid is reported. The growth of a polymer film at room temperature was achieved via plasmon-induced homolysis of alkoxyamines covalently attached to the surface of plasmon-active gold gratings at room temperature. Control of temperature, finite-difference time-domain method simulation of plasmon intensity distribution shift during polymerization, electron paramagnetic resonance experiments and other assays provide strong support for the plasmon-initiated mechanism of NMP. We demonstrated not only the control of the resulting polymer thickness but also the preparation of a surface-enhanced Raman spectroscopy chip for the detection of glycoproteins as a powerful example of plasmon-assisted NMP potential.

Original languageEnglish
Pages (from-to)12414-12419
Number of pages6
JournalJournal of Materials Chemistry A
Volume7
Issue number20
DOIs
Publication statusPublished - 1 Jan 2019

Fingerprint

Polymerization
Glycoproteins
Finite difference time domain method
Polymer films
Gold
Temperature
Block copolymers
Paramagnetic resonance
Raman spectroscopy
Assays
Polymers
Acids
Experiments

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP) : A method for preparation of functional surfaces. / Guselnikova, Olga; Marque, Sylvain R.A.; Tretyakov, Evgeny V.; Mares, David; Jerabek, Vitezslav; Audran, Gérard; Joly, Jean Patrick; Trusova, Marina; Svorcik, Vaclav; Lyutakov, Oleksiy; Postnikov, Pavel.

In: Journal of Materials Chemistry A, Vol. 7, No. 20, 01.01.2019, p. 12414-12419.

Research output: Contribution to journalArticle

Guselnikova, Olga ; Marque, Sylvain R.A. ; Tretyakov, Evgeny V. ; Mares, David ; Jerabek, Vitezslav ; Audran, Gérard ; Joly, Jean Patrick ; Trusova, Marina ; Svorcik, Vaclav ; Lyutakov, Oleksiy ; Postnikov, Pavel. / Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP) : A method for preparation of functional surfaces. In: Journal of Materials Chemistry A. 2019 ; Vol. 7, No. 20. pp. 12414-12419.
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