Tubular and microcylindrical platinum electrodes for amperometric detection of aminobiphenyls and aminonaphthalenes in HPLC

Abstract

Platinum electrodes in microcylindrical and tubular arrangements were compared as working electrodes for amperometric detection of 2-aminobiphenyl, 4-aminobiphenyl, 1-aminonaphthalene, and 2-aminonaphthalene in HPLC. Factors influencing separation efficiency are favourable for microcylindrical arrangement while tubular arrangement exhibits higher sensitivities and lower limits of detection. These are in the range of 0.0078-0.027μmolL^-1 for tubular, and 0.11-0.42μmolL^-1 for microcylindrical arrangement. Further, a new method with nanomolar detection limits was proposed for determination of tested compounds in urine using solid phase extraction for preliminary separation and preconcentration of the analytes.

Original language	English
Pages (from-to)	687-696
Number of pages	10
Journal	Electroanalysis
Volume	26
Issue number	4
DOIs	https://doi.org/10.1002/elan.201300579
Publication status	Published - 1 Jan 2014
Externally published	Yes

Keywords

Aminoderivatives of polycyclic aromatic hydrocarbons
Electrochemical detection
Platinum electrode
Solid phase extraction
Urine

ASJC Scopus subject areas

Analytical Chemistry
Electrochemistry

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10.1002/elan.201300579

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@article{d1ba3882106e48858bf0c9925f0c178a,

title = "Tubular and microcylindrical platinum electrodes for amperometric detection of aminobiphenyls and aminonaphthalenes in HPLC",

abstract = "Platinum electrodes in microcylindrical and tubular arrangements were compared as working electrodes for amperometric detection of 2-aminobiphenyl, 4-aminobiphenyl, 1-aminonaphthalene, and 2-aminonaphthalene in HPLC. Factors influencing separation efficiency are favourable for microcylindrical arrangement while tubular arrangement exhibits higher sensitivities and lower limits of detection. These are in the range of 0.0078-0.027μmolL-1 for tubular, and 0.11-0.42μmolL-1 for microcylindrical arrangement. Further, a new method with nanomolar detection limits was proposed for determination of tested compounds in urine using solid phase extraction for preliminary separation and preconcentration of the analytes.",

keywords = "Aminoderivatives of polycyclic aromatic hydrocarbons, Electrochemical detection, Platinum electrode, Solid phase extraction, Urine",

author = "Jaroslava Zavazalova and Hana Dejmkova and Jiri Barek and Karolina Peckova",

year = "2014",

month = jan,

day = "1",

doi = "10.1002/elan.201300579",

language = "English",

volume = "26",

pages = "687--696",

journal = "Macromolecular Chemistry and Physics",

issn = "1040-0397",

publisher = "Wiley-VCH Verlag",

number = "4",

}

TY - JOUR

T1 - Tubular and microcylindrical platinum electrodes for amperometric detection of aminobiphenyls and aminonaphthalenes in HPLC

AU - Zavazalova, Jaroslava

AU - Dejmkova, Hana

AU - Barek, Jiri

AU - Peckova, Karolina

PY - 2014/1/1

Y1 - 2014/1/1

N2 - Platinum electrodes in microcylindrical and tubular arrangements were compared as working electrodes for amperometric detection of 2-aminobiphenyl, 4-aminobiphenyl, 1-aminonaphthalene, and 2-aminonaphthalene in HPLC. Factors influencing separation efficiency are favourable for microcylindrical arrangement while tubular arrangement exhibits higher sensitivities and lower limits of detection. These are in the range of 0.0078-0.027μmolL-1 for tubular, and 0.11-0.42μmolL-1 for microcylindrical arrangement. Further, a new method with nanomolar detection limits was proposed for determination of tested compounds in urine using solid phase extraction for preliminary separation and preconcentration of the analytes.

AB - Platinum electrodes in microcylindrical and tubular arrangements were compared as working electrodes for amperometric detection of 2-aminobiphenyl, 4-aminobiphenyl, 1-aminonaphthalene, and 2-aminonaphthalene in HPLC. Factors influencing separation efficiency are favourable for microcylindrical arrangement while tubular arrangement exhibits higher sensitivities and lower limits of detection. These are in the range of 0.0078-0.027μmolL-1 for tubular, and 0.11-0.42μmolL-1 for microcylindrical arrangement. Further, a new method with nanomolar detection limits was proposed for determination of tested compounds in urine using solid phase extraction for preliminary separation and preconcentration of the analytes.

KW - Aminoderivatives of polycyclic aromatic hydrocarbons

KW - Electrochemical detection

KW - Platinum electrode

KW - Solid phase extraction

KW - Urine

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DO - 10.1002/elan.201300579

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VL - 26

SP - 687

EP - 696

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

SN - 1040-0397

IS - 4