Tribological behaviour of RF-magnetron sputter deposited hydroxyapatite coatings in physiological solution

Mihaela Dinu, Anna A. Ivanova, Maria A. Surmeneva, Mariana Braic, Alexander I. Tyurin, Viorel Braic, Roman A. Surmenev, Alina Vladescu

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The aim of the paper is to explore the tribological performance of hydroxyapatite (HA) coatings deposited by radio frequency (RF) magnetron sputtering on AZ31 magnesium alloy (96% Mg, 3% Al, 0.7% Zn, 0.3% Mn) for biomedical applications. In this study, the position of the samples on a substrate holder, relative to a target erosion zone was taken into consideration in order to elucidate its impact on the coating characteristics, such as composition, morphology, surface topography and tribology. Substrate rotation and arc-movement were foreseen in the experimental set-up to increase the uniformity of thin film properties. The deposited HA thin films were revealed to exhibit an increase of the Ca/P ratio from 1.83 to 1.97, a decrease of (002) texture and thickness, as the samples were shifted towards the target erosion zone. By coatings, the roughness of Mg alloy was decreased (Ra Mg alloy=31.3 nm; Ra coating=29 nm and 21 nm). The coating placed in the centre of the substrate holder showed high hardness and Young's modulus (H =8.3±0.9 GPa; E=89±10 GPa) than the coating prepared under the target erosion zone (H =6.9±1.1 GPa; E=75±6 GPa). The coating deposited under target erosion zone exhibits superior friction behaviour in simulated body fluid environment, with the friction coefficient (μ) of 0.184, while the sample located in the centre of the substrate holder possesses the friction coefficient (0.306) comparable to the AZ31 substrate (0.307). The low wear rate was determined in the case of coating deposited under target erosion zone (4.83×10−5 mm3 N−1 m−1) than uncoated AZ31 substrate (0.00518 mm3 N−1 m−1) or than coating placed in the centre of the substrate holder (0.00294 mm3 N−1 m−1).

Original languageEnglish
Pages (from-to)6858-6867
Number of pages10
JournalCeramics International
Volume43
Issue number9
DOIs
Publication statusPublished - 15 Jun 2017

Fingerprint

Durapatite
Hydroxyapatite
Coatings
Erosion
Substrates
Friction
Thin films
Tribology
Body fluids
Surface topography
Magnesium alloys
Magnetron sputtering
Textures
Elastic moduli
Surface roughness
Hardness
Wear of materials
Chemical analysis

Keywords

  • A: Films
  • C: Friction, Wear resistance
  • D: Apatite
  • E: Biomedical applications

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Process Chemistry and Technology
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Tribological behaviour of RF-magnetron sputter deposited hydroxyapatite coatings in physiological solution. / Dinu, Mihaela; Ivanova, Anna A.; Surmeneva, Maria A.; Braic, Mariana; Tyurin, Alexander I.; Braic, Viorel; Surmenev, Roman A.; Vladescu, Alina.

In: Ceramics International, Vol. 43, No. 9, 15.06.2017, p. 6858-6867.

Research output: Contribution to journalArticle

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abstract = "The aim of the paper is to explore the tribological performance of hydroxyapatite (HA) coatings deposited by radio frequency (RF) magnetron sputtering on AZ31 magnesium alloy (96{\%} Mg, 3{\%} Al, 0.7{\%} Zn, 0.3{\%} Mn) for biomedical applications. In this study, the position of the samples on a substrate holder, relative to a target erosion zone was taken into consideration in order to elucidate its impact on the coating characteristics, such as composition, morphology, surface topography and tribology. Substrate rotation and arc-movement were foreseen in the experimental set-up to increase the uniformity of thin film properties. The deposited HA thin films were revealed to exhibit an increase of the Ca/P ratio from 1.83 to 1.97, a decrease of (002) texture and thickness, as the samples were shifted towards the target erosion zone. By coatings, the roughness of Mg alloy was decreased (Ra Mg alloy=31.3 nm; Ra coating=29 nm and 21 nm). The coating placed in the centre of the substrate holder showed high hardness and Young's modulus (H =8.3±0.9 GPa; E=89±10 GPa) than the coating prepared under the target erosion zone (H =6.9±1.1 GPa; E=75±6 GPa). The coating deposited under target erosion zone exhibits superior friction behaviour in simulated body fluid environment, with the friction coefficient (μ) of 0.184, while the sample located in the centre of the substrate holder possesses the friction coefficient (0.306) comparable to the AZ31 substrate (0.307). The low wear rate was determined in the case of coating deposited under target erosion zone (4.83×10−5 mm3 N−1 m−1) than uncoated AZ31 substrate (0.00518 mm3 N−1 m−1) or than coating placed in the centre of the substrate holder (0.00294 mm3 N−1 m−1).",
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AU - Tyurin, Alexander I.

AU - Braic, Viorel

AU - Surmenev, Roman A.

AU - Vladescu, Alina

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AB - The aim of the paper is to explore the tribological performance of hydroxyapatite (HA) coatings deposited by radio frequency (RF) magnetron sputtering on AZ31 magnesium alloy (96% Mg, 3% Al, 0.7% Zn, 0.3% Mn) for biomedical applications. In this study, the position of the samples on a substrate holder, relative to a target erosion zone was taken into consideration in order to elucidate its impact on the coating characteristics, such as composition, morphology, surface topography and tribology. Substrate rotation and arc-movement were foreseen in the experimental set-up to increase the uniformity of thin film properties. The deposited HA thin films were revealed to exhibit an increase of the Ca/P ratio from 1.83 to 1.97, a decrease of (002) texture and thickness, as the samples were shifted towards the target erosion zone. By coatings, the roughness of Mg alloy was decreased (Ra Mg alloy=31.3 nm; Ra coating=29 nm and 21 nm). The coating placed in the centre of the substrate holder showed high hardness and Young's modulus (H =8.3±0.9 GPa; E=89±10 GPa) than the coating prepared under the target erosion zone (H =6.9±1.1 GPa; E=75±6 GPa). The coating deposited under target erosion zone exhibits superior friction behaviour in simulated body fluid environment, with the friction coefficient (μ) of 0.184, while the sample located in the centre of the substrate holder possesses the friction coefficient (0.306) comparable to the AZ31 substrate (0.307). The low wear rate was determined in the case of coating deposited under target erosion zone (4.83×10−5 mm3 N−1 m−1) than uncoated AZ31 substrate (0.00518 mm3 N−1 m−1) or than coating placed in the centre of the substrate holder (0.00294 mm3 N−1 m−1).

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