Abstract
An expression has been derived for the time dependence of the NMR line shape for systems with many-site chemical exchange in the absence of spin-spin coupling, in a zero saturation limit. The dynamics of variation of the NMR line shape with time is considered in detail for the case of two-site chemical exchange. Mathematica programs have been designed for numerical simulation of the NMR spectra of chemical exchange systems. The analytical expressions obtained are useful for NMR line shape simulations for systems with photoinduced chemical exchange.
| Original language | English |
|---|---|
| Pages (from-to) | 442-446 |
| Number of pages | 5 |
| Journal | Journal of Structural Chemistry |
| Volume | 47 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - May 2006 |
| Externally published | Yes |
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Keywords
- Chemical exchange
- Dynamic NMR
- Many-site exchange
- NMR line shape analysis procedures
- Photoinduced chemical exchange
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
Cite this
Time dependence of the NMR line shape for systems with chemical exchange in a zero saturation limit. / Babailov, S. P.; Mainichev, D. A.
In: Journal of Structural Chemistry, Vol. 47, No. 3, 05.2006, p. 442-446.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Time dependence of the NMR line shape for systems with chemical exchange in a zero saturation limit
AU - Babailov, S. P.
AU - Mainichev, D. A.
PY - 2006/5
Y1 - 2006/5
N2 - An expression has been derived for the time dependence of the NMR line shape for systems with many-site chemical exchange in the absence of spin-spin coupling, in a zero saturation limit. The dynamics of variation of the NMR line shape with time is considered in detail for the case of two-site chemical exchange. Mathematica programs have been designed for numerical simulation of the NMR spectra of chemical exchange systems. The analytical expressions obtained are useful for NMR line shape simulations for systems with photoinduced chemical exchange.
AB - An expression has been derived for the time dependence of the NMR line shape for systems with many-site chemical exchange in the absence of spin-spin coupling, in a zero saturation limit. The dynamics of variation of the NMR line shape with time is considered in detail for the case of two-site chemical exchange. Mathematica programs have been designed for numerical simulation of the NMR spectra of chemical exchange systems. The analytical expressions obtained are useful for NMR line shape simulations for systems with photoinduced chemical exchange.
KW - Chemical exchange
KW - Dynamic NMR
KW - Many-site exchange
KW - NMR line shape analysis procedures
KW - Photoinduced chemical exchange
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UR - http://www.scopus.com/inward/citedby.url?scp=33750729255&partnerID=8YFLogxK
U2 - 10.1007/s10947-006-0320-x
DO - 10.1007/s10947-006-0320-x
M3 - Article
VL - 47
SP - 442
EP - 446
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 3
ER -