Thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature

S. P. Babailov

    Research output: Contribution to journalArticle

    10 Citations (Scopus)

    Abstract

    A study is conducted to demonstrate thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. The use of the paramagnetic lanthanide probe of molecular dynamics can have a broad meaning. The study investigates the intermolecular exchange of H2O along with more detailed examination of the substantial temperature dependence of PCSs in tris-pivaloyltrifluoracetonate thulium(III) .

    Original languageEnglish
    Pages (from-to)476-478
    Number of pages3
    JournalSensors and Actuators, B: Chemical
    Volume233
    DOIs
    Publication statusPublished - 5 Oct 2016

    Keywords

    • Complexes of lanthanides
    • Free energy of activation
    • Kinetics of chemical exchange
    • Lanthanide-induced shifts in NMR spectra
    • Temperature sensitive NMR lanthanide paramagnetic probe

    ASJC Scopus subject areas

    • Electrical and Electronic Engineering
    • Condensed Matter Physics
    • Electronic, Optical and Magnetic Materials
    • Metals and Alloys
    • Surfaces, Coatings and Films
    • Materials Chemistry
    • Instrumentation

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