Abstract
A study is conducted to demonstrate thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. The use of the paramagnetic lanthanide probe of molecular dynamics can have a broad meaning. The study investigates the intermolecular exchange of H2O along with more detailed examination of the substantial temperature dependence of PCSs in tris-pivaloyltrifluoracetonate thulium(III) .
Original language | English |
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Pages (from-to) | 476-478 |
Number of pages | 3 |
Journal | Sensors and Actuators, B: Chemical |
Volume | 233 |
DOIs | |
Publication status | Published - 5 Oct 2016 |
Keywords
- Complexes of lanthanides
- Free energy of activation
- Kinetics of chemical exchange
- Lanthanide-induced shifts in NMR spectra
- Temperature sensitive NMR lanthanide paramagnetic probe
ASJC Scopus subject areas
- Electrical and Electronic Engineering
- Condensed Matter Physics
- Electronic, Optical and Magnetic Materials
- Metals and Alloys
- Surfaces, Coatings and Films
- Materials Chemistry
- Instrumentation