Thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature

Abstract

A study is conducted to demonstrate thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. The use of the paramagnetic lanthanide probe of molecular dynamics can have a broad meaning. The study investigates the intermolecular exchange of H₂O along with more detailed examination of the substantial temperature dependence of PCSs in tris-pivaloyltrifluoracetonate thulium(III) .

Original language	English
Pages (from-to)	476-478
Number of pages	3
Journal	Sensors and Actuators, B: Chemical
Volume	233
DOIs	https://doi.org/10.1016/j.snb.2016.04.009
Publication status	Published - 5 Oct 2016

Keywords

Complexes of lanthanides
Free energy of activation
Kinetics of chemical exchange
Lanthanide-induced shifts in NMR spectra
Temperature sensitive NMR lanthanide paramagnetic probe

ASJC Scopus subject areas

Electrical and Electronic Engineering
Condensed Matter Physics
Electronic, Optical and Magnetic Materials
Metals and Alloys
Surfaces, Coatings and Films
Materials Chemistry
Instrumentation

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10.1016/j.snb.2016.04.009

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Babailov, S. P. (2016). Thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. Sensors and Actuators, B: Chemical, 233, 476-478. https://doi.org/10.1016/j.snb.2016.04.009

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keywords = "Complexes of lanthanides, Free energy of activation, Kinetics of chemical exchange, Lanthanide-induced shifts in NMR spectra, Temperature sensitive NMR lanthanide paramagnetic probe",

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AB - A study is conducted to demonstrate thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. The use of the paramagnetic lanthanide probe of molecular dynamics can have a broad meaning. The study investigates the intermolecular exchange of H2O along with more detailed examination of the substantial temperature dependence of PCSs in tris-pivaloyltrifluoracetonate thulium(III) .

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KW - Lanthanide-induced shifts in NMR spectra

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