Thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature

S. P. Babailov

    Research output: Contribution to journalArticle

    10 Citations (Scopus)

    Abstract

    A study is conducted to demonstrate thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. The use of the paramagnetic lanthanide probe of molecular dynamics can have a broad meaning. The study investigates the intermolecular exchange of H2O along with more detailed examination of the substantial temperature dependence of PCSs in tris-pivaloyltrifluoracetonate thulium(III) .

    Original languageEnglish
    Pages (from-to)476-478
    Number of pages3
    JournalSensors and Actuators, B: Chemical
    Volume233
    DOIs
    Publication statusPublished - 5 Oct 2016

    Fingerprint

    Thulium
    thulium
    reagents
    Molecular dynamics
    Nuclear magnetic resonance
    molecular dynamics
    Lanthanoid Series Elements
    nuclear magnetic resonance
    probes
    Rare earth elements
    examination
    Temperature
    temperature dependence
    temperature

    Keywords

    • Complexes of lanthanides
    • Free energy of activation
    • Kinetics of chemical exchange
    • Lanthanide-induced shifts in NMR spectra
    • Temperature sensitive NMR lanthanide paramagnetic probe

    ASJC Scopus subject areas

    • Electrical and Electronic Engineering
    • Condensed Matter Physics
    • Electronic, Optical and Magnetic Materials
    • Metals and Alloys
    • Surfaces, Coatings and Films
    • Materials Chemistry
    • Instrumentation

    Cite this

    @article{4e258d42a0f6414b87135bb4d656f608,
    title = "Thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature",
    abstract = "A study is conducted to demonstrate thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. The use of the paramagnetic lanthanide probe of molecular dynamics can have a broad meaning. The study investigates the intermolecular exchange of H2O along with more detailed examination of the substantial temperature dependence of PCSs in tris-pivaloyltrifluoracetonate thulium(III) .",
    keywords = "Complexes of lanthanides, Free energy of activation, Kinetics of chemical exchange, Lanthanide-induced shifts in NMR spectra, Temperature sensitive NMR lanthanide paramagnetic probe",
    author = "Babailov, {S. P.}",
    year = "2016",
    month = "10",
    day = "5",
    doi = "10.1016/j.snb.2016.04.009",
    language = "English",
    volume = "233",
    pages = "476--478",
    journal = "Sensors and Actuators, B: Chemical",
    issn = "0925-4005",
    publisher = "Elsevier",

    }

    TY - JOUR

    T1 - Thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature

    AU - Babailov, S. P.

    PY - 2016/10/5

    Y1 - 2016/10/5

    N2 - A study is conducted to demonstrate thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. The use of the paramagnetic lanthanide probe of molecular dynamics can have a broad meaning. The study investigates the intermolecular exchange of H2O along with more detailed examination of the substantial temperature dependence of PCSs in tris-pivaloyltrifluoracetonate thulium(III) .

    AB - A study is conducted to demonstrate thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. The use of the paramagnetic lanthanide probe of molecular dynamics can have a broad meaning. The study investigates the intermolecular exchange of H2O along with more detailed examination of the substantial temperature dependence of PCSs in tris-pivaloyltrifluoracetonate thulium(III) .

    KW - Complexes of lanthanides

    KW - Free energy of activation

    KW - Kinetics of chemical exchange

    KW - Lanthanide-induced shifts in NMR spectra

    KW - Temperature sensitive NMR lanthanide paramagnetic probe

    UR - http://www.scopus.com/inward/record.url?scp=84964692133&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=84964692133&partnerID=8YFLogxK

    U2 - 10.1016/j.snb.2016.04.009

    DO - 10.1016/j.snb.2016.04.009

    M3 - Article

    AN - SCOPUS:84964692133

    VL - 233

    SP - 476

    EP - 478

    JO - Sensors and Actuators, B: Chemical

    JF - Sensors and Actuators, B: Chemical

    SN - 0925-4005

    ER -