Thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature

S. P. Babailov

Research output: Contribution to journal › Article

Abstract

A study is conducted to demonstrate thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. The use of the paramagnetic lanthanide probe of molecular dynamics can have a broad meaning. The study investigates the intermolecular exchange of H₂O along with more detailed examination of the substantial temperature dependence of PCSs in tris-pivaloyltrifluoracetonate thulium(III) .

Original language	English
Pages (from-to)	476-478
Number of pages	3
Journal	Sensors and Actuators, B: Chemical
Volume	233
DOIs	https://doi.org/10.1016/j.snb.2016.04.009
Publication status	Published - 5 Oct 2016

Fingerprint

Keywords

Complexes of lanthanides
Free energy of activation
Kinetics of chemical exchange
Lanthanide-induced shifts in NMR spectra
Temperature sensitive NMR lanthanide paramagnetic probe

ASJC Scopus subject areas

Electrical and Electronic Engineering
Condensed Matter Physics
Electronic, Optical and Magnetic Materials
Metals and Alloys
Surfaces, Coatings and Films
Materials Chemistry
Instrumentation

Cite this

Babailov, S. P. (2016). Thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. Sensors and Actuators, B: Chemical, 233, 476-478. https://doi.org/10.1016/j.snb.2016.04.009

@article{4e258d42a0f6414b87135bb4d656f608,

title = "Thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature",

abstract = "A study is conducted to demonstrate thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. The use of the paramagnetic lanthanide probe of molecular dynamics can have a broad meaning. The study investigates the intermolecular exchange of H2O along with more detailed examination of the substantial temperature dependence of PCSs in tris-pivaloyltrifluoracetonate thulium(III) .",

keywords = "Complexes of lanthanides, Free energy of activation, Kinetics of chemical exchange, Lanthanide-induced shifts in NMR spectra, Temperature sensitive NMR lanthanide paramagnetic probe",

author = "Babailov, {S. P.}",

year = "2016",

month = "10",

day = "5",

doi = "10.1016/j.snb.2016.04.009",

language = "English",

volume = "233",

pages = "476--478",

journal = "Sensors and Actuators, B: Chemical",

issn = "0925-4005",

publisher = "Elsevier",

}

TY - JOUR

T1 - Thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature

AU - Babailov, S. P.

PY - 2016/10/5

Y1 - 2016/10/5

N2 - A study is conducted to demonstrate thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. The use of the paramagnetic lanthanide probe of molecular dynamics can have a broad meaning. The study investigates the intermolecular exchange of H2O along with more detailed examination of the substantial temperature dependence of PCSs in tris-pivaloyltrifluoracetonate thulium(III) .

AB - A study is conducted to demonstrate thulium diketonate as NMR paramagnetic probe for moderately fast molecular dynamics and supersensitive reagent for in situ control of temperature. The use of the paramagnetic lanthanide probe of molecular dynamics can have a broad meaning. The study investigates the intermolecular exchange of H2O along with more detailed examination of the substantial temperature dependence of PCSs in tris-pivaloyltrifluoracetonate thulium(III) .

KW - Complexes of lanthanides

KW - Free energy of activation

KW - Kinetics of chemical exchange

KW - Lanthanide-induced shifts in NMR spectra

KW - Temperature sensitive NMR lanthanide paramagnetic probe

UR - http://www.scopus.com/inward/record.url?scp=84964692133&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84964692133&partnerID=8YFLogxK

U2 - 10.1016/j.snb.2016.04.009

DO - 10.1016/j.snb.2016.04.009

M3 - Article

AN - SCOPUS:84964692133

VL - 233

SP - 476

EP - 478

JO - Sensors and Actuators, B: Chemical

JF - Sensors and Actuators, B: Chemical

SN - 0925-4005

ER -

Access to Document

10.1016/j.snb.2016.04.009