Thermally activated transformations in metastable alumina coatings prepared by magnetron sputtering

P. Zeman, Š Zuzjaková, J. Blažek, R. Čerstvý, J. Musil

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

An as-deposited metastable structure of alumina coatings can be of essential importance for the transformation processes occurring in the coatings during their annealing. The present study focuses on thermal stability and phase transformations in magnetron sputtered alumina coatings with different as-deposited structures characterized by different ratios of an amorphous a-Al2O3 to crystalline γ-Al2O3 phase. Purely amorphous, purely γ-phase and γ-phase/amorphous coatings were investigated by a combination of differential scanning calorimetry (40°C/min in air) and ex-situ X-ray diffraction analyses. Indentation testing and optical characterization were also carried out. In the coatings with a purely or partially amorphous as-deposited structure two exothermic transformations occurred. An a-to-γ transformation proceeded at ~900°C while a γ-to-α transformation proceeded at ~1200°C. In the crystalline γ-phase as-deposited coating the γ-to-α transformation was the only exothermic transformation observed at the same temperature of ~1200°C. Independently of the as-deposited structure, the γ-to-α transformation was accompanied by the formation of the intermediate metastable θ phase without any detectable heat released. Measured changes in transformation enthalpies for the a-to-γ and γ-to-α transformations were close to each other while the activation energy was higher for the γ-to-α transformation. Hardness, effective Young's modulus and refractive index showed a tendency to increase with a decreasing amount of an amorphous phase in the coating.

Original languageEnglish
Pages (from-to)7-13
Number of pages7
JournalSurface and Coatings Technology
Volume240
DOIs
Publication statusPublished - 15 Feb 2014

Fingerprint

Aluminum Oxide
Magnetron sputtering
magnetron sputtering
Alumina
aluminum oxides
coatings
Coatings
Crystalline materials
Metastable phases
Indentation
Differential scanning calorimetry
Enthalpy
Refractive index
Thermodynamic stability
Activation energy
Elastic moduli
Phase transitions
Hardness
Annealing
X ray diffraction

Keywords

  • Alumina coatings
  • Differential scanning calorimetry
  • Metastable phases
  • Phase transformations
  • Sputtering

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Thermally activated transformations in metastable alumina coatings prepared by magnetron sputtering. / Zeman, P.; Zuzjaková, Š; Blažek, J.; Čerstvý, R.; Musil, J.

In: Surface and Coatings Technology, Vol. 240, 15.02.2014, p. 7-13.

Research output: Contribution to journalArticle

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