TY - JOUR
T1 - Thermal stability of ammonium chlorocobaltates(II)
AU - Zhilina, O. V.
AU - D'Yachenko, A. N.
AU - Kozik, V. V.
AU - Kraidenko, R. I.
PY - 2014
Y1 - 2014
N2 - The thermal destruction of ammonium penta-, tetra-, and trichlorocobaltates(II) was studied. Thermogravimetric analysis (TGA) data was used to calculate the thermal destruction activation energy, which was 8.6 kJ/mol for (NH4)3CoCl5, 14.8 kJ/mol for (NH4)2CoCl4, and 117.4 kJ/mol for NH 4CoCl3. The decomposition enthalpy of 35.9 kJ/mol for (NH4)3CoCl5, 12.1 kJ/mol for (NH 4)2CoCl4, and 166.3 kJ/mol for NH 4CoCl3 was determined from differential scanning calorimetry (DSC) data.
AB - The thermal destruction of ammonium penta-, tetra-, and trichlorocobaltates(II) was studied. Thermogravimetric analysis (TGA) data was used to calculate the thermal destruction activation energy, which was 8.6 kJ/mol for (NH4)3CoCl5, 14.8 kJ/mol for (NH4)2CoCl4, and 117.4 kJ/mol for NH 4CoCl3. The decomposition enthalpy of 35.9 kJ/mol for (NH4)3CoCl5, 12.1 kJ/mol for (NH 4)2CoCl4, and 166.3 kJ/mol for NH 4CoCl3 was determined from differential scanning calorimetry (DSC) data.
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U2 - 10.1134/S0036023614060217
DO - 10.1134/S0036023614060217
M3 - Article
AN - SCOPUS:84902953605
VL - 59
SP - 536
EP - 540
JO - Russian Journal of Inorganic Chemistry
JF - Russian Journal of Inorganic Chemistry
SN - 0036-0236
IS - 6
ER -