Thermal stability of ammonium chlorocobaltates(II)

Abstract

The thermal destruction of ammonium penta-, tetra-, and trichlorocobaltates(II) was studied. Thermogravimetric analysis (TGA) data was used to calculate the thermal destruction activation energy, which was 8.6 kJ/mol for (NH₄)₃CoCl₅, 14.8 kJ/mol for (NH₄)₂CoCl₄, and 117.4 kJ/mol for NH ₄CoCl₃. The decomposition enthalpy of 35.9 kJ/mol for (NH₄)₃CoCl₅, 12.1 kJ/mol for (NH ₄)₂CoCl₄, and 166.3 kJ/mol for NH ₄CoCl₃ was determined from differential scanning calorimetry (DSC) data.

Original language	English
Pages (from-to)	536-540
Number of pages	5
Journal	Russian Journal of Inorganic Chemistry
Volume	59
Issue number	6
DOIs	https://doi.org/10.1134/S0036023614060217
Publication status	Published - 2014

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1134/S0036023614060217

Fingerprint Dive into the research topics of 'Thermal stability of ammonium chlorocobaltates(II)'. Together they form a unique fingerprint.

Cite this

@article{a2d10b81ec0d408f8186bd1385374e48,

title = "Thermal stability of ammonium chlorocobaltates(II)",

abstract = "The thermal destruction of ammonium penta-, tetra-, and trichlorocobaltates(II) was studied. Thermogravimetric analysis (TGA) data was used to calculate the thermal destruction activation energy, which was 8.6 kJ/mol for (NH4)3CoCl5, 14.8 kJ/mol for (NH4)2CoCl4, and 117.4 kJ/mol for NH 4CoCl3. The decomposition enthalpy of 35.9 kJ/mol for (NH4)3CoCl5, 12.1 kJ/mol for (NH 4)2CoCl4, and 166.3 kJ/mol for NH 4CoCl3 was determined from differential scanning calorimetry (DSC) data.",

author = "Zhilina, {O. V.} and D'Yachenko, {A. N.} and Kozik, {V. V.} and Kraidenko, {R. I.}",

year = "2014",

doi = "10.1134/S0036023614060217",

language = "English",

volume = "59",

pages = "536--540",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "6",

}

TY - JOUR

T1 - Thermal stability of ammonium chlorocobaltates(II)

AU - Zhilina, O. V.

AU - D'Yachenko, A. N.

AU - Kozik, V. V.

AU - Kraidenko, R. I.

PY - 2014

Y1 - 2014

N2 - The thermal destruction of ammonium penta-, tetra-, and trichlorocobaltates(II) was studied. Thermogravimetric analysis (TGA) data was used to calculate the thermal destruction activation energy, which was 8.6 kJ/mol for (NH4)3CoCl5, 14.8 kJ/mol for (NH4)2CoCl4, and 117.4 kJ/mol for NH 4CoCl3. The decomposition enthalpy of 35.9 kJ/mol for (NH4)3CoCl5, 12.1 kJ/mol for (NH 4)2CoCl4, and 166.3 kJ/mol for NH 4CoCl3 was determined from differential scanning calorimetry (DSC) data.

AB - The thermal destruction of ammonium penta-, tetra-, and trichlorocobaltates(II) was studied. Thermogravimetric analysis (TGA) data was used to calculate the thermal destruction activation energy, which was 8.6 kJ/mol for (NH4)3CoCl5, 14.8 kJ/mol for (NH4)2CoCl4, and 117.4 kJ/mol for NH 4CoCl3. The decomposition enthalpy of 35.9 kJ/mol for (NH4)3CoCl5, 12.1 kJ/mol for (NH 4)2CoCl4, and 166.3 kJ/mol for NH 4CoCl3 was determined from differential scanning calorimetry (DSC) data.

UR - http://www.scopus.com/inward/record.url?scp=84902953605&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84902953605&partnerID=8YFLogxK

U2 - 10.1134/S0036023614060217

DO - 10.1134/S0036023614060217

M3 - Article

AN - SCOPUS:84902953605

VL - 59

SP - 536

EP - 540

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 6

ER -