Thermal stability of ammonium chlorocobaltates(II)

O. V. Zhilina, A. N. D'Yachenko, V. V. Kozik, R. I. Kraidenko

Research output: Contribution to journal › Article

Abstract

The thermal destruction of ammonium penta-, tetra-, and trichlorocobaltates(II) was studied. Thermogravimetric analysis (TGA) data was used to calculate the thermal destruction activation energy, which was 8.6 kJ/mol for (NH4)3CoCl5, 14.8 kJ/mol for (NH4)2CoCl4, and 117.4 kJ/mol for NH 4CoCl3. The decomposition enthalpy of 35.9 kJ/mol for (NH4)3CoCl5, 12.1 kJ/mol for (NH 4)2CoCl4, and 166.3 kJ/mol for NH 4CoCl3 was determined from differential scanning calorimetry (DSC) data.

Original languageEnglish
Pages (from-to)536-540
Number of pages5
JournalRussian Journal of Inorganic Chemistry
Volume59
Issue number6
DOIs
Publication statusPublished - 2014

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Ammonium Compounds
destruction
Thermodynamic stability
thermal stability
Thermogravimetric analysis
Differential scanning calorimetry
Enthalpy
heat measurement
Activation energy
enthalpy
activation energy
Decomposition
decomposition
scanning
Hot Temperature

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Zhilina, O. V., D'Yachenko, A. N., Kozik, V. V., & Kraidenko, R. I. (2014). Thermal stability of ammonium chlorocobaltates(II). Russian Journal of Inorganic Chemistry, 59(6), 536-540. https://doi.org/10.1134/S0036023614060217

Thermal stability of ammonium chlorocobaltates(II). / Zhilina, O. V.; D'Yachenko, A. N.; Kozik, V. V.; Kraidenko, R. I.

In: Russian Journal of Inorganic Chemistry, Vol. 59, No. 6, 2014, p. 536-540.

Research output: Contribution to journal › Article

Zhilina, OV, D'Yachenko, AN, Kozik, VV & Kraidenko, RI 2014, 'Thermal stability of ammonium chlorocobaltates(II)', Russian Journal of Inorganic Chemistry, vol. 59, no. 6, pp. 536-540. https://doi.org/10.1134/S0036023614060217
Zhilina OV, D'Yachenko AN, Kozik VV, Kraidenko RI. Thermal stability of ammonium chlorocobaltates(II). Russian Journal of Inorganic Chemistry. 2014;59(6):536-540. https://doi.org/10.1134/S0036023614060217
Zhilina, O. V. ; D'Yachenko, A. N. ; Kozik, V. V. ; Kraidenko, R. I. / Thermal stability of ammonium chlorocobaltates(II). In: Russian Journal of Inorganic Chemistry. 2014 ; Vol. 59, No. 6. pp. 536-540.
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