Thermal stability of ammonium chlorocobaltates(II)

O. V. Zhilina, A. N. D'Yachenko, V. V. Kozik, R. I. Kraidenko

Research output: Contribution to journalArticle

Abstract

The thermal destruction of ammonium penta-, tetra-, and trichlorocobaltates(II) was studied. Thermogravimetric analysis (TGA) data was used to calculate the thermal destruction activation energy, which was 8.6 kJ/mol for (NH4)3CoCl5, 14.8 kJ/mol for (NH4)2CoCl4, and 117.4 kJ/mol for NH 4CoCl3. The decomposition enthalpy of 35.9 kJ/mol for (NH4)3CoCl5, 12.1 kJ/mol for (NH 4)2CoCl4, and 166.3 kJ/mol for NH 4CoCl3 was determined from differential scanning calorimetry (DSC) data.

Original languageEnglish
Pages (from-to)536-540
Number of pages5
JournalRussian Journal of Inorganic Chemistry
Volume59
Issue number6
DOIs
Publication statusPublished - 2014

Fingerprint

Ammonium Compounds
destruction
Thermodynamic stability
thermal stability
Thermogravimetric analysis
Differential scanning calorimetry
Enthalpy
heat measurement
Activation energy
enthalpy
activation energy
Decomposition
decomposition
scanning
Hot Temperature

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Zhilina, O. V., D'Yachenko, A. N., Kozik, V. V., & Kraidenko, R. I. (2014). Thermal stability of ammonium chlorocobaltates(II). Russian Journal of Inorganic Chemistry, 59(6), 536-540. https://doi.org/10.1134/S0036023614060217

Thermal stability of ammonium chlorocobaltates(II). / Zhilina, O. V.; D'Yachenko, A. N.; Kozik, V. V.; Kraidenko, R. I.

In: Russian Journal of Inorganic Chemistry, Vol. 59, No. 6, 2014, p. 536-540.

Research output: Contribution to journalArticle

Zhilina, OV, D'Yachenko, AN, Kozik, VV & Kraidenko, RI 2014, 'Thermal stability of ammonium chlorocobaltates(II)', Russian Journal of Inorganic Chemistry, vol. 59, no. 6, pp. 536-540. https://doi.org/10.1134/S0036023614060217
Zhilina, O. V. ; D'Yachenko, A. N. ; Kozik, V. V. ; Kraidenko, R. I. / Thermal stability of ammonium chlorocobaltates(II). In: Russian Journal of Inorganic Chemistry. 2014 ; Vol. 59, No. 6. pp. 536-540.
@article{a2d10b81ec0d408f8186bd1385374e48,
title = "Thermal stability of ammonium chlorocobaltates(II)",
abstract = "The thermal destruction of ammonium penta-, tetra-, and trichlorocobaltates(II) was studied. Thermogravimetric analysis (TGA) data was used to calculate the thermal destruction activation energy, which was 8.6 kJ/mol for (NH4)3CoCl5, 14.8 kJ/mol for (NH4)2CoCl4, and 117.4 kJ/mol for NH 4CoCl3. The decomposition enthalpy of 35.9 kJ/mol for (NH4)3CoCl5, 12.1 kJ/mol for (NH 4)2CoCl4, and 166.3 kJ/mol for NH 4CoCl3 was determined from differential scanning calorimetry (DSC) data.",
author = "Zhilina, {O. V.} and D'Yachenko, {A. N.} and Kozik, {V. V.} and Kraidenko, {R. I.}",
year = "2014",
doi = "10.1134/S0036023614060217",
language = "English",
volume = "59",
pages = "536--540",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "6",

}

TY - JOUR

T1 - Thermal stability of ammonium chlorocobaltates(II)

AU - Zhilina, O. V.

AU - D'Yachenko, A. N.

AU - Kozik, V. V.

AU - Kraidenko, R. I.

PY - 2014

Y1 - 2014

N2 - The thermal destruction of ammonium penta-, tetra-, and trichlorocobaltates(II) was studied. Thermogravimetric analysis (TGA) data was used to calculate the thermal destruction activation energy, which was 8.6 kJ/mol for (NH4)3CoCl5, 14.8 kJ/mol for (NH4)2CoCl4, and 117.4 kJ/mol for NH 4CoCl3. The decomposition enthalpy of 35.9 kJ/mol for (NH4)3CoCl5, 12.1 kJ/mol for (NH 4)2CoCl4, and 166.3 kJ/mol for NH 4CoCl3 was determined from differential scanning calorimetry (DSC) data.

AB - The thermal destruction of ammonium penta-, tetra-, and trichlorocobaltates(II) was studied. Thermogravimetric analysis (TGA) data was used to calculate the thermal destruction activation energy, which was 8.6 kJ/mol for (NH4)3CoCl5, 14.8 kJ/mol for (NH4)2CoCl4, and 117.4 kJ/mol for NH 4CoCl3. The decomposition enthalpy of 35.9 kJ/mol for (NH4)3CoCl5, 12.1 kJ/mol for (NH 4)2CoCl4, and 166.3 kJ/mol for NH 4CoCl3 was determined from differential scanning calorimetry (DSC) data.

UR - http://www.scopus.com/inward/record.url?scp=84902953605&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84902953605&partnerID=8YFLogxK

U2 - 10.1134/S0036023614060217

DO - 10.1134/S0036023614060217

M3 - Article

AN - SCOPUS:84902953605

VL - 59

SP - 536

EP - 540

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 6

ER -