The use of redox reactions in the analysis of dyes and dye intermediates. XIX. Determination of some water-insoluble azo pigments in acetonitrile using TAST and DP polarography

J. Barek, A. Berka, V. Borek

Research output: Contribution to journalArticle

Abstract

The TAST and DP polarographic behavior of some water-insoluble azo pigments in acetonitrile in the presence of tris(hydroxymethyl)aminomethane was investigated. It has been found that this substance decreases the adverse effect of small changes in the concentration of water and proton donors on the slope of the calibration curve by functioning as a buffer. It has been verified that a higher sensitivity of DPP enables its use for the determination of the test azo pigments after their elution from TLC plates used for a preliminary separation.

Original languageEnglish
Pages (from-to)161-165
Number of pages5
JournalMicrochemical Journal
Volume32
Issue number2
DOIs
Publication statusPublished - 1 Jan 1985
Externally publishedYes

Fingerprint

Polarographic analysis
Redox reactions
Pigments
Coloring Agents
Tromethamine
Water
Protons
Buffers
Calibration
acetonitrile

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy

Cite this

@article{d84fe2b5a01c4045b52ec2aa86741520,
title = "The use of redox reactions in the analysis of dyes and dye intermediates. XIX. Determination of some water-insoluble azo pigments in acetonitrile using TAST and DP polarography",
abstract = "The TAST and DP polarographic behavior of some water-insoluble azo pigments in acetonitrile in the presence of tris(hydroxymethyl)aminomethane was investigated. It has been found that this substance decreases the adverse effect of small changes in the concentration of water and proton donors on the slope of the calibration curve by functioning as a buffer. It has been verified that a higher sensitivity of DPP enables its use for the determination of the test azo pigments after their elution from TLC plates used for a preliminary separation.",
author = "J. Barek and A. Berka and V. Borek",
year = "1985",
month = "1",
day = "1",
doi = "10.1016/0026-265X(85)90072-4",
language = "English",
volume = "32",
pages = "161--165",
journal = "Microchemical Journal",
issn = "0026-265X",
publisher = "Elsevier Inc.",
number = "2",

}

TY - JOUR

T1 - The use of redox reactions in the analysis of dyes and dye intermediates. XIX. Determination of some water-insoluble azo pigments in acetonitrile using TAST and DP polarography

AU - Barek, J.

AU - Berka, A.

AU - Borek, V.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - The TAST and DP polarographic behavior of some water-insoluble azo pigments in acetonitrile in the presence of tris(hydroxymethyl)aminomethane was investigated. It has been found that this substance decreases the adverse effect of small changes in the concentration of water and proton donors on the slope of the calibration curve by functioning as a buffer. It has been verified that a higher sensitivity of DPP enables its use for the determination of the test azo pigments after their elution from TLC plates used for a preliminary separation.

AB - The TAST and DP polarographic behavior of some water-insoluble azo pigments in acetonitrile in the presence of tris(hydroxymethyl)aminomethane was investigated. It has been found that this substance decreases the adverse effect of small changes in the concentration of water and proton donors on the slope of the calibration curve by functioning as a buffer. It has been verified that a higher sensitivity of DPP enables its use for the determination of the test azo pigments after their elution from TLC plates used for a preliminary separation.

UR - http://www.scopus.com/inward/record.url?scp=46549090737&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=46549090737&partnerID=8YFLogxK

U2 - 10.1016/0026-265X(85)90072-4

DO - 10.1016/0026-265X(85)90072-4

M3 - Article

AN - SCOPUS:46549090737

VL - 32

SP - 161

EP - 165

JO - Microchemical Journal

JF - Microchemical Journal

SN - 0026-265X

IS - 2

ER -