The electronic structures of the SbCl5L and SnCl4L2 complexes are studied by the PM3 method. The results are compared with the relevant 35Cl NQR, 121Sb NQR, and Mossbauer data. The calculated nuclear quadrupole coupling constants agree well with their experimental values. The energies of formation of the donor-acceptor bonds are correlated with the amounts of transferred electron density. The observed correlation relationships are different for the cis and trans complexes.
|Number of pages||5|
|Journal||Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya|
|Publication status||Published - 1 Oct 1997|
ASJC Scopus subject areas
- Chemical Engineering(all)