The reaction of alkynes with dimethyl sulfoxide, halogenated hydrocarbons and sulfur trioxide

Victor O. Rogachev, Victor D. Filimonov, Mehman S. Yusubov, Anne Jager

Research output: Contribution to journalArticle

Abstract

1,2-Disubstituted alkynes are converted in CCl4 or CHCl3 with dimethyl sulfoxide in the presence of sulfur trioxide into the corresponding (E, Z)-1-chloro-2-methylthio-ethenes. The reaction of 1,2-diphenylethyne with CHBr3, DMSO, and dioxane sulfotrioxide gives (E, Z)-1,2-dimethylthio-1,2- diphenylethene.

Original languageEnglish
Pages (from-to)511-519
Number of pages9
JournalJournal of Sulfur Chemistry
Volume29
Issue number5
DOIs
Publication statusPublished - 1 Oct 2008

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Halogenated Hydrocarbons
Alkynes
Dimethyl Sulfoxide
sulfur trioxide

Keywords

  • Alkynes
  • Dimethyl sulfoxide
  • Halogenmethanes
  • Multicomponent reactions
  • Sulfur trioxide

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

The reaction of alkynes with dimethyl sulfoxide, halogenated hydrocarbons and sulfur trioxide. / Rogachev, Victor O.; Filimonov, Victor D.; Yusubov, Mehman S.; Jager, Anne.

In: Journal of Sulfur Chemistry, Vol. 29, No. 5, 01.10.2008, p. 511-519.

Research output: Contribution to journalArticle

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AB - 1,2-Disubstituted alkynes are converted in CCl4 or CHCl3 with dimethyl sulfoxide in the presence of sulfur trioxide into the corresponding (E, Z)-1-chloro-2-methylthio-ethenes. The reaction of 1,2-diphenylethyne with CHBr3, DMSO, and dioxane sulfotrioxide gives (E, Z)-1,2-dimethylthio-1,2- diphenylethene.

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