The photophysical properties of molecules with triple bonds

V. F. Razumov, V. A. Sazhnikov, M. V. Alfimov, I. L. Kotlyarevskii, M. I. Bardamova, S. F. Vasilevskii

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

1. The relative contribution of the triple bond to conjugation in the tert-butyl derivtives of tolan, diphenylacetylene, 4-tert-butyl-4′-(phenylethynyl)biphenyl, and 1,4-bis(p-tert-butylphenylethynyl) benzene is comparable with the contribution from a double bond or a phenyl ring. 2. The introduction of a phenyl ring into compounds with triple bonds leads to an increase in the fluorescence. 3. The reduction in the phosphorescence lifetime resulting from the increase in the number of triple bonds in the molecule is the result of an increase in the constant for the radiationless triplet-singlet transition.

Original languageEnglish
Pages (from-to)329-333
Number of pages5
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume28
Issue number2
DOIs
Publication statusPublished - 1 Feb 1979
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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