TY - GEN
T1 - The oxidative destruction of substandard tributyl phosphate organic solutions under mild conditions
AU - Volgina, Tatiana
AU - Posvyashchennaya, Anzhelika
AU - Frantcuzskaia, Evgeniia
PY - 2017/1/1
Y1 - 2017/1/1
N2 - The liquid-phase oxidative destruction of 30% solution of tributyl phosphate in kerosene has been carried out under the action of oxidants generated by the electrical current which has been passed through 40% aqueous solutions of the sulfuric acid under atmospheric pressure and at temperature of 50 °C. Tributyl phosphate and its solvent have been partly destroyed due to the electrochemical processes on the lead electrodes, however, a large part of components has been subjected to deep oxidation in the volume of electrolyte. As a result of oxidation, the following final products have been formed: phosphoric acid, mono- and dicarboxylic acids, carbon dioxide and water.
AB - The liquid-phase oxidative destruction of 30% solution of tributyl phosphate in kerosene has been carried out under the action of oxidants generated by the electrical current which has been passed through 40% aqueous solutions of the sulfuric acid under atmospheric pressure and at temperature of 50 °C. Tributyl phosphate and its solvent have been partly destroyed due to the electrochemical processes on the lead electrodes, however, a large part of components has been subjected to deep oxidation in the volume of electrolyte. As a result of oxidation, the following final products have been formed: phosphoric acid, mono- and dicarboxylic acids, carbon dioxide and water.
KW - Direct oxidation
KW - Extractant
KW - Hydrolysis
KW - Indirect oxidation
KW - Sulfuric acid electrolysis
KW - Tributyl phosphate
UR - http://www.scopus.com/inward/record.url?scp=85027016353&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85027016353&partnerID=8YFLogxK
U2 - 10.4028/www.scientific.net/KEM.743.305
DO - 10.4028/www.scientific.net/KEM.743.305
M3 - Conference contribution
AN - SCOPUS:85027016353
SN - 9783035711356
T3 - Key Engineering Materials
SP - 305
EP - 309
BT - High Technology
A2 - Osokin, Georgii E.
A2 - Kulinich, Ekaterina A.
PB - Trans Tech Publications Ltd
T2 - 5th International Science and Engineering Conference on High Technology: Research and Applications, HTRA 2016
Y2 - 5 December 2016 through 7 December 2016
ER -