Abstract
The liquid-phase oxidative destruction of 30% solution of tributyl phosphate in kerosene has been carried out under the action of oxidants generated by the electrical current which has been passed through 40% aqueous solutions of the sulfuric acid under atmospheric pressure and at temperature of 50 °C. Tributyl phosphate and its solvent have been partly destroyed due to the electrochemical processes on the lead electrodes, however, a large part of components has been subjected to deep oxidation in the volume of electrolyte. As a result of oxidation, the following final products have been formed: phosphoric acid, mono- and dicarboxylic acids, carbon dioxide and water.
| Original language | English |
|---|---|
| Title of host publication | High Technology |
| Subtitle of host publication | Research and Applications 2016 - HTRA-2016 |
| Editors | Georgii E. Osokin, Ekaterina A. Kulinich |
| Publisher | Trans Tech Publications Ltd |
| Pages | 305-309 |
| Number of pages | 5 |
| ISBN (Print) | 9783035711356 |
| DOIs | |
| Publication status | Published - 1 Jan 2017 |
| Event | 5th International Science and Engineering Conference on High Technology: Research and Applications, HTRA 2016 - Tomsk, Russian Federation Duration: 5 Dec 2016 → 7 Dec 2016 |
Publication series
| Name | Key Engineering Materials |
|---|---|
| Volume | 743 KEM |
| ISSN (Print) | 1013-9826 |
Conference
| Conference | 5th International Science and Engineering Conference on High Technology: Research and Applications, HTRA 2016 |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 5.12.16 → 7.12.16 |
Fingerprint
Keywords
- Direct oxidation
- Extractant
- Hydrolysis
- Indirect oxidation
- Sulfuric acid electrolysis
- Tributyl phosphate
ASJC Scopus subject areas
- Materials Science(all)
- Mechanics of Materials
- Mechanical Engineering
Cite this
The oxidative destruction of substandard tributyl phosphate organic solutions under mild conditions. / Volgina, Tatiana; Posvyashchennaya, Anzhelika; Frantcuzskaia, Evgeniia.
High Technology: Research and Applications 2016 - HTRA-2016. ed. / Georgii E. Osokin; Ekaterina A. Kulinich. Trans Tech Publications Ltd, 2017. p. 305-309 (Key Engineering Materials; Vol. 743 KEM).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - The oxidative destruction of substandard tributyl phosphate organic solutions under mild conditions
AU - Volgina, Tatiana
AU - Posvyashchennaya, Anzhelika
AU - Frantcuzskaia, Evgeniia
PY - 2017/1/1
Y1 - 2017/1/1
N2 - The liquid-phase oxidative destruction of 30% solution of tributyl phosphate in kerosene has been carried out under the action of oxidants generated by the electrical current which has been passed through 40% aqueous solutions of the sulfuric acid under atmospheric pressure and at temperature of 50 °C. Tributyl phosphate and its solvent have been partly destroyed due to the electrochemical processes on the lead electrodes, however, a large part of components has been subjected to deep oxidation in the volume of electrolyte. As a result of oxidation, the following final products have been formed: phosphoric acid, mono- and dicarboxylic acids, carbon dioxide and water.
AB - The liquid-phase oxidative destruction of 30% solution of tributyl phosphate in kerosene has been carried out under the action of oxidants generated by the electrical current which has been passed through 40% aqueous solutions of the sulfuric acid under atmospheric pressure and at temperature of 50 °C. Tributyl phosphate and its solvent have been partly destroyed due to the electrochemical processes on the lead electrodes, however, a large part of components has been subjected to deep oxidation in the volume of electrolyte. As a result of oxidation, the following final products have been formed: phosphoric acid, mono- and dicarboxylic acids, carbon dioxide and water.
KW - Direct oxidation
KW - Extractant
KW - Hydrolysis
KW - Indirect oxidation
KW - Sulfuric acid electrolysis
KW - Tributyl phosphate
UR - http://www.scopus.com/inward/record.url?scp=85027016353&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85027016353&partnerID=8YFLogxK
U2 - 10.4028/www.scientific.net/KEM.743.305
DO - 10.4028/www.scientific.net/KEM.743.305
M3 - Conference contribution
AN - SCOPUS:85027016353
SN - 9783035711356
T3 - Key Engineering Materials
SP - 305
EP - 309
BT - High Technology
A2 - Osokin, Georgii E.
A2 - Kulinich, Ekaterina A.
PB - Trans Tech Publications Ltd
ER -