The oxidative destruction of substandard tributyl phosphate organic solutions under mild conditions

Tatiana Volgina, Anzhelika Posvyashchennaya, Evgeniia Frantcuzskaia

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The liquid-phase oxidative destruction of 30% solution of tributyl phosphate in kerosene has been carried out under the action of oxidants generated by the electrical current which has been passed through 40% aqueous solutions of the sulfuric acid under atmospheric pressure and at temperature of 50 °C. Tributyl phosphate and its solvent have been partly destroyed due to the electrochemical processes on the lead electrodes, however, a large part of components has been subjected to deep oxidation in the volume of electrolyte. As a result of oxidation, the following final products have been formed: phosphoric acid, mono- and dicarboxylic acids, carbon dioxide and water.

Original languageEnglish
Title of host publicationHigh Technology
Subtitle of host publicationResearch and Applications 2016 - HTRA-2016
EditorsGeorgii E. Osokin, Ekaterina A. Kulinich
PublisherTrans Tech Publications Ltd
Pages305-309
Number of pages5
ISBN (Print)9783035711356
DOIs
Publication statusPublished - 1 Jan 2017
Event5th International Science and Engineering Conference on High Technology: Research and Applications, HTRA 2016 - Tomsk, Russian Federation
Duration: 5 Dec 20167 Dec 2016

Publication series

NameKey Engineering Materials
Volume743 KEM
ISSN (Print)1013-9826

Conference

Conference5th International Science and Engineering Conference on High Technology: Research and Applications, HTRA 2016
CountryRussian Federation
CityTomsk
Period5.12.167.12.16

Fingerprint

Phosphates
Oxidation
Dicarboxylic Acids
Kerosene
Phosphoric acid
Oxidants
Sulfuric acid
Carbon Dioxide
Electrolytes
Atmospheric pressure
Carbon dioxide
Electrodes
Acids
Water
Liquids
Temperature
tributyl phosphate
phosphoric acid
sulfuric acid

Keywords

  • Direct oxidation
  • Extractant
  • Hydrolysis
  • Indirect oxidation
  • Sulfuric acid electrolysis
  • Tributyl phosphate

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Volgina, T., Posvyashchennaya, A., & Frantcuzskaia, E. (2017). The oxidative destruction of substandard tributyl phosphate organic solutions under mild conditions. In G. E. Osokin, & E. A. Kulinich (Eds.), High Technology: Research and Applications 2016 - HTRA-2016 (pp. 305-309). (Key Engineering Materials; Vol. 743 KEM). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/KEM.743.305

The oxidative destruction of substandard tributyl phosphate organic solutions under mild conditions. / Volgina, Tatiana; Posvyashchennaya, Anzhelika; Frantcuzskaia, Evgeniia.

High Technology: Research and Applications 2016 - HTRA-2016. ed. / Georgii E. Osokin; Ekaterina A. Kulinich. Trans Tech Publications Ltd, 2017. p. 305-309 (Key Engineering Materials; Vol. 743 KEM).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Volgina, T, Posvyashchennaya, A & Frantcuzskaia, E 2017, The oxidative destruction of substandard tributyl phosphate organic solutions under mild conditions. in GE Osokin & EA Kulinich (eds), High Technology: Research and Applications 2016 - HTRA-2016. Key Engineering Materials, vol. 743 KEM, Trans Tech Publications Ltd, pp. 305-309, 5th International Science and Engineering Conference on High Technology: Research and Applications, HTRA 2016, Tomsk, Russian Federation, 5.12.16. https://doi.org/10.4028/www.scientific.net/KEM.743.305
Volgina T, Posvyashchennaya A, Frantcuzskaia E. The oxidative destruction of substandard tributyl phosphate organic solutions under mild conditions. In Osokin GE, Kulinich EA, editors, High Technology: Research and Applications 2016 - HTRA-2016. Trans Tech Publications Ltd. 2017. p. 305-309. (Key Engineering Materials). https://doi.org/10.4028/www.scientific.net/KEM.743.305
Volgina, Tatiana ; Posvyashchennaya, Anzhelika ; Frantcuzskaia, Evgeniia. / The oxidative destruction of substandard tributyl phosphate organic solutions under mild conditions. High Technology: Research and Applications 2016 - HTRA-2016. editor / Georgii E. Osokin ; Ekaterina A. Kulinich. Trans Tech Publications Ltd, 2017. pp. 305-309 (Key Engineering Materials).
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