TY - JOUR
T1 - The luminescence performance of Tb3+ doped ABS-BGP glasses excited by different type of energy sources
AU - Yao, Guanpeng
AU - Valiev, Damir
AU - Li, Shasha
AU - Stepanov, Sergey
AU - Li, Chun
AU - Lin, Hai
AU - Liu, Lina
AU - Zhou, Yanyan
AU - Zeng, Fanming
AU - Su, Zhongmin
PY - 2020/10
Y1 - 2020/10
N2 - Transparent ABS-BGP (Al2O3–B2O3–SiO2–BaCO3-Gd2O3–P2O5) glasses doped with different level of Tb3+ concentrations (from 0 to 12 mol.%) were synthesized by the high-temperature melting method. The luminescent and energy transfer properties were investigated by transmittance, photoluminescence, cathodoluminescence (CL) and X-ray excited luminescence spectra. The optimal concentration of Tb3+ ions in ABS-BGP glasses excited by both ultraviolet light, electron beam, and X-ray excitation was also determined. The decay time of 543 nm main emission band of Tb3+ doped glasses decrease in the range from 1.66 ± 0.005 to 1.18 ± 0.005 ms with increasing of Tb3+ions. The energy transfer mechanism was discussed, and the corresponding critical distances for Tb3+–Tb3+ ion pairs were calculated. The integral scintillation efficiency of the 10 mol% Tb3+-doped ABS-BGP glass sample reach 63.9% of the Bi4Ge3O12 (BGO) standard crystal.
AB - Transparent ABS-BGP (Al2O3–B2O3–SiO2–BaCO3-Gd2O3–P2O5) glasses doped with different level of Tb3+ concentrations (from 0 to 12 mol.%) were synthesized by the high-temperature melting method. The luminescent and energy transfer properties were investigated by transmittance, photoluminescence, cathodoluminescence (CL) and X-ray excited luminescence spectra. The optimal concentration of Tb3+ ions in ABS-BGP glasses excited by both ultraviolet light, electron beam, and X-ray excitation was also determined. The decay time of 543 nm main emission band of Tb3+ doped glasses decrease in the range from 1.66 ± 0.005 to 1.18 ± 0.005 ms with increasing of Tb3+ions. The energy transfer mechanism was discussed, and the corresponding critical distances for Tb3+–Tb3+ ion pairs were calculated. The integral scintillation efficiency of the 10 mol% Tb3+-doped ABS-BGP glass sample reach 63.9% of the Bi4Ge3O12 (BGO) standard crystal.
KW - Cathodoluminescence
KW - Decay time
KW - Energy transfer mechanism
KW - Glass
KW - Radioluminescence
KW - Tb ions
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U2 - 10.1016/j.jlumin.2020.117514
DO - 10.1016/j.jlumin.2020.117514
M3 - Article
AN - SCOPUS:85087748012
VL - 226
JO - Journal of Luminescence
JF - Journal of Luminescence
SN - 0022-2313
M1 - 117514
ER -