The influence of intense ultrasound applied during pressing on the optical and cathodoluminescent properties of conventionally sintered YSZ ceramics

Research output: Contribution to journalArticle

Abstract

The aim of the present work was to investigate the effect of the ultrasonic treatment on the optical and cathodoluminescent properties of translucent ZrO2-8 mol.% Y2O3 (YSZ) ceramics obtained by conventional sintering of the pressed compacts. Treatment by intense ultrasound during dry pressing of the YSZ nanopowder leads to an increase in the relative density, a decrease in the pore size and an increase in the grain size of the sintered ceramics. It was shown that when the ultrasonic treatment is applied, the optical absorption cutoff wavelength of the sintered material is shifted to longer wavelengths, while the optical density of the material increases over the whole measurement spectrum. Samples subjected to ultrasonic treatment during pressing show higher intensity of luminescence than those obtained without the use of ultrasound, the shape of the luminescence spectra remaining unchanged. A correlation was obtained between the integral intensity of cathodoluminescence and the vacancy concentration in the sintered YSZ.

Original languageEnglish
Pages (from-to)166-171
Number of pages6
JournalUltrasonics Sonochemistry
Volume50
DOIs
Publication statusPublished - 1 Jan 2019

Fingerprint

ultrasonic processing
Ceramics
pressing
yttria-stabilized zirconia
Ultrasonics
ceramics
Luminescence
optical properties
luminescence
Specific Gravity
optical density
cathodoluminescence
wavelengths
sintering
optical absorption
cut-off
grain size
Wavelength
Density (optical)
Cathodoluminescence

Keywords

  • Cathodoluminescent properties
  • Ceramics
  • Ultrasound treatment
  • Yttria-stabilized zirconia

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Radiology Nuclear Medicine and imaging
  • Acoustics and Ultrasonics

Cite this

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title = "The influence of intense ultrasound applied during pressing on the optical and cathodoluminescent properties of conventionally sintered YSZ ceramics",
abstract = "The aim of the present work was to investigate the effect of the ultrasonic treatment on the optical and cathodoluminescent properties of translucent ZrO2-8 mol.{\%} Y2O3 (YSZ) ceramics obtained by conventional sintering of the pressed compacts. Treatment by intense ultrasound during dry pressing of the YSZ nanopowder leads to an increase in the relative density, a decrease in the pore size and an increase in the grain size of the sintered ceramics. It was shown that when the ultrasonic treatment is applied, the optical absorption cutoff wavelength of the sintered material is shifted to longer wavelengths, while the optical density of the material increases over the whole measurement spectrum. Samples subjected to ultrasonic treatment during pressing show higher intensity of luminescence than those obtained without the use of ultrasound, the shape of the luminescence spectra remaining unchanged. A correlation was obtained between the integral intensity of cathodoluminescence and the vacancy concentration in the sintered YSZ.",
keywords = "Cathodoluminescent properties, Ceramics, Ultrasound treatment, Yttria-stabilized zirconia",
author = "Khasanov, {O. L.} and Dvilis, {E. S.} and Polisadova, {E. F.} and Stepanov, {S. A.} and Valiev, {D. T.} and Paygin, {V. D.} and Dudina, {D. V.}",
year = "2019",
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T1 - The influence of intense ultrasound applied during pressing on the optical and cathodoluminescent properties of conventionally sintered YSZ ceramics

AU - Khasanov, O. L.

AU - Dvilis, E. S.

AU - Polisadova, E. F.

AU - Stepanov, S. A.

AU - Valiev, D. T.

AU - Paygin, V. D.

AU - Dudina, D. V.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - The aim of the present work was to investigate the effect of the ultrasonic treatment on the optical and cathodoluminescent properties of translucent ZrO2-8 mol.% Y2O3 (YSZ) ceramics obtained by conventional sintering of the pressed compacts. Treatment by intense ultrasound during dry pressing of the YSZ nanopowder leads to an increase in the relative density, a decrease in the pore size and an increase in the grain size of the sintered ceramics. It was shown that when the ultrasonic treatment is applied, the optical absorption cutoff wavelength of the sintered material is shifted to longer wavelengths, while the optical density of the material increases over the whole measurement spectrum. Samples subjected to ultrasonic treatment during pressing show higher intensity of luminescence than those obtained without the use of ultrasound, the shape of the luminescence spectra remaining unchanged. A correlation was obtained between the integral intensity of cathodoluminescence and the vacancy concentration in the sintered YSZ.

AB - The aim of the present work was to investigate the effect of the ultrasonic treatment on the optical and cathodoluminescent properties of translucent ZrO2-8 mol.% Y2O3 (YSZ) ceramics obtained by conventional sintering of the pressed compacts. Treatment by intense ultrasound during dry pressing of the YSZ nanopowder leads to an increase in the relative density, a decrease in the pore size and an increase in the grain size of the sintered ceramics. It was shown that when the ultrasonic treatment is applied, the optical absorption cutoff wavelength of the sintered material is shifted to longer wavelengths, while the optical density of the material increases over the whole measurement spectrum. Samples subjected to ultrasonic treatment during pressing show higher intensity of luminescence than those obtained without the use of ultrasound, the shape of the luminescence spectra remaining unchanged. A correlation was obtained between the integral intensity of cathodoluminescence and the vacancy concentration in the sintered YSZ.

KW - Cathodoluminescent properties

KW - Ceramics

KW - Ultrasound treatment

KW - Yttria-stabilized zirconia

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