The high-resolution fourier transform spectrum of dideuterated methane CH2D2 in the region between 1900 and 2400 cm-1

Oleg N. Ulenikov, Eizi Hirota, Mitsuru Akiyama, S. Alanko, M. Koivusaari, R. Anttila, G. Guelachvili, R. N. Tolchenov

Research output: Contribution to journalArticle

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Abstract

The infrared spectrum of doubly deuterated methane CH2D2 has been recorded in the region from 1900 to 2400 cm-1 at almost Doppler-limited resolution by using two high-resolution Fourier transform spectrometers. The vibrational bands observed include 2ν4, ν4 + ν7, 2ν7, ν2, ν8, ν4 + ν9, and ν7 + ν9, which were analyzed by taking into account Coriolis and Fermi interactions among them and also those with ν4 + ν5, ν3 + ν7, and ν5 + ν7. Most of the centrifugal distortion constants were constrained to appropriate values, while the vibrational term value and three rotational constants in each of the seven excited states were adjusted along with Coriolis and Fermi interaction parameters by the least-squares analysis of the observed spectrum. The vibration-rotation interaction constants αs thus determined for the ν2 and ν8 states were combined with those of other fundamental states already published to calculate the equilibrium C-H distance.

Original languageEnglish
Pages (from-to)423-432
Number of pages10
JournalJournal of Molecular Spectroscopy
Volume180
Issue number2
DOIs
Publication statusPublished - 1 Jan 1996

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Methane
Excited states
Spectrometers
Fourier transforms
methane
Infrared radiation
high resolution
interactions
infrared spectra
spectrometers
vibration
excitation

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

Cite this

The high-resolution fourier transform spectrum of dideuterated methane CH2D2 in the region between 1900 and 2400 cm-1 . / Ulenikov, Oleg N.; Hirota, Eizi; Akiyama, Mitsuru; Alanko, S.; Koivusaari, M.; Anttila, R.; Guelachvili, G.; Tolchenov, R. N.

In: Journal of Molecular Spectroscopy, Vol. 180, No. 2, 01.01.1996, p. 423-432.

Research output: Contribution to journalArticle

Ulenikov, ON, Hirota, E, Akiyama, M, Alanko, S, Koivusaari, M, Anttila, R, Guelachvili, G & Tolchenov, RN 1996, 'The high-resolution fourier transform spectrum of dideuterated methane CH2D2 in the region between 1900 and 2400 cm-1 ', Journal of Molecular Spectroscopy, vol. 180, no. 2, pp. 423-432. https://doi.org/10.1006/jmsp.1996.0266
Ulenikov, Oleg N. ; Hirota, Eizi ; Akiyama, Mitsuru ; Alanko, S. ; Koivusaari, M. ; Anttila, R. ; Guelachvili, G. ; Tolchenov, R. N. / The high-resolution fourier transform spectrum of dideuterated methane CH2D2 in the region between 1900 and 2400 cm-1 In: Journal of Molecular Spectroscopy. 1996 ; Vol. 180, No. 2. pp. 423-432.
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