The first example of a domino Diels-Alder/retro-Diels-Alder reaction of 1,3-dienic δ-sultones with alkynes: A simple synthesis of m-terphenyl dicarboxy derivatives from 4,6-diphenyl-[1,2]oxathiine 2,2-dioxide

Jens Gaitzsch, Victor O. Rogachev, Peter Metz, Mekhman S. Yusubov, Victor D. Filimonov, Olga Kataeva

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

[1,1′;3′,1″]Terphenyl-4′,5′-dicarboxylic acid derivatives were prepared from 1,3-dienic δ-sultone 4,6-diphenyl-[1,2] oxathiine 2,2-dioxide via Diels-Alder/retro-Diels-Alder reaction with dimethyl acetylenedicarboxylate under thermal, microwave or high-pressure activation.

Original languageEnglish
Pages (from-to)4-9
Number of pages6
JournalJournal of Sulfur Chemistry
Volume30
Issue number1
DOIs
Publication statusPublished - 1 Feb 2009

Keywords

  • Alkynes
  • Diels-Alder reaction
  • High pressure
  • m-terphenyl derivatives
  • Sultones

ASJC Scopus subject areas

  • Chemistry(all)

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