The first azaindatrane and unprecedented structural features

Pavel L. Shutov, Sergey S. Karlov, Klaus Harms, Oleg Kh Poleshchuk, Jörg Lorberth, Galina S. Zaitseva

    Research output: Contribution to journalArticle

    12 Citations (Scopus)

    Abstract

    The reaction between [In(NEt2)3]2 and N(CH2CH2NMeH)3 yields the N,N′,N″-trimethylazaindatrane dimer [N(CH2-CH2NMe)3In]2 (1). The composition and structure of 1 were established by 1H and 13C NMR spectroscopy as well as by an X-ray diffraction study. The X-ray structure shows that both indium atoms are pentacoordinate, with widely differing In-N distances. The structural parameters of 1 were compared with those obtained from a computational study. (

    Original languageEnglish
    Pages (from-to)1507-1510
    Number of pages4
    JournalEuropean Journal of Inorganic Chemistry
    Issue number8
    DOIs
    Publication statusPublished - 1 Jan 2003

    Fingerprint

    Indium
    Dimers
    Nuclear magnetic resonance spectroscopy
    X ray diffraction
    X rays
    Atoms
    Chemical analysis

    Keywords

    • Azametallatranes
    • Indium
    • Tripodal ligands

    ASJC Scopus subject areas

    • Inorganic Chemistry

    Cite this

    Shutov, P. L., Karlov, S. S., Harms, K., Poleshchuk, O. K., Lorberth, J., & Zaitseva, G. S. (2003). The first azaindatrane and unprecedented structural features. European Journal of Inorganic Chemistry, (8), 1507-1510. https://doi.org/10.1002/ejic.200390194

    The first azaindatrane and unprecedented structural features. / Shutov, Pavel L.; Karlov, Sergey S.; Harms, Klaus; Poleshchuk, Oleg Kh; Lorberth, Jörg; Zaitseva, Galina S.

    In: European Journal of Inorganic Chemistry, No. 8, 01.01.2003, p. 1507-1510.

    Research output: Contribution to journalArticle

    Shutov, PL, Karlov, SS, Harms, K, Poleshchuk, OK, Lorberth, J & Zaitseva, GS 2003, 'The first azaindatrane and unprecedented structural features', European Journal of Inorganic Chemistry, no. 8, pp. 1507-1510. https://doi.org/10.1002/ejic.200390194
    Shutov PL, Karlov SS, Harms K, Poleshchuk OK, Lorberth J, Zaitseva GS. The first azaindatrane and unprecedented structural features. European Journal of Inorganic Chemistry. 2003 Jan 1;(8):1507-1510. https://doi.org/10.1002/ejic.200390194
    Shutov, Pavel L. ; Karlov, Sergey S. ; Harms, Klaus ; Poleshchuk, Oleg Kh ; Lorberth, Jörg ; Zaitseva, Galina S. / The first azaindatrane and unprecedented structural features. In: European Journal of Inorganic Chemistry. 2003 ; No. 8. pp. 1507-1510.
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