The first azaindatrane and unprecedented structural features

Pavel L. Shutov, Sergey S. Karlov, Klaus Harms, Oleg Kh Poleshchuk, Jörg Lorberth, Galina S. Zaitseva

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    Abstract

    The reaction between [In(NEt2)3]2 and N(CH2CH2NMeH)3 yields the N,N′,N″-trimethylazaindatrane dimer [N(CH2-CH2NMe)3In]2 (1). The composition and structure of 1 were established by 1H and 13C NMR spectroscopy as well as by an X-ray diffraction study. The X-ray structure shows that both indium atoms are pentacoordinate, with widely differing In-N distances. The structural parameters of 1 were compared with those obtained from a computational study. (

    Original languageEnglish
    Pages (from-to)1507-1510
    Number of pages4
    JournalEuropean Journal of Inorganic Chemistry
    Issue number8
    DOIs
    Publication statusPublished - 1 Jan 2003

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    Keywords

    • Azametallatranes
    • Indium
    • Tripodal ligands

    ASJC Scopus subject areas

    • Inorganic Chemistry

    Cite this

    Shutov, P. L., Karlov, S. S., Harms, K., Poleshchuk, O. K., Lorberth, J., & Zaitseva, G. S. (2003). The first azaindatrane and unprecedented structural features. European Journal of Inorganic Chemistry, (8), 1507-1510. https://doi.org/10.1002/ejic.200390194