The correlation between the ³⁵Cl NQR frequencies and the energies of inner levels in tin(IV) compounds

O. Kh Poleshchuk, I. Latoshinska

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Abstract

A search for the correlations between the ³⁵Cl NQR frequencies and the energies of inner Sn3d_5/2 and Cl 2p_3/2 levels in organotin compounds is carried out. Relationships between the energies of inner levels and the effective charges on the tin and chlorine atoms are calculated at the PM3 level. These relationships were used to determine the correlations between the energies of inner levels and the ClKα shifts in the X-ray fluorescence spectra of complexes SnCl₄L₂.

Original language	English
Pages (from-to)	775-778
Number of pages	4
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	22
Issue number	11
Publication status	Published - Nov 1996

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Inorganic Chemistry

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Poleshchuk, O. K., & Latoshinska, I. (1996). The correlation between the ³⁵Cl NQR frequencies and the energies of inner levels in tin(IV) compounds. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 22(11), 775-778.

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abstract = "A search for the correlations between the 35Cl NQR frequencies and the energies of inner Sn3d5/2 and Cl 2p3/2 levels in organotin compounds is carried out. Relationships between the energies of inner levels and the effective charges on the tin and chlorine atoms are calculated at the PM3 level. These relationships were used to determine the correlations between the energies of inner levels and the ClKα shifts in the X-ray fluorescence spectra of complexes SnCl4L2.",

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The correlation between the 35Cl NQR frequencies and the energies of inner levels in tin(IV) compounds

Abstract

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The correlation between the ³⁵Cl NQR frequencies and the energies of inner levels in tin(IV) compounds